1957
Horne, R. A.; Holm, R. H.; Meyers, M. D.  "Adsorption of Zinc(II) on Anion Exchange Resins.  II. Stoichiometry, Thermodynamics, Loading Studies, Dowex-2 Adsorption, and the Factors Influencing the Rate of the Adsorption Process,” J. Phys. Chem. 1957, 61, 1655-1661.

Horne, R. A.; Holm, R. H.; Meyers, M. D.  "Adsorption of Zinc(II) on Anion Exchange Resins.  III. The Adsorption from Bromide, Fluoride, Cyanide, Oxalate, Acetate, Nitrate, Phosphate, Sulfate, and Alkaline Media; the Perchlorate Effect, and the Adsorption from Mixed Solvent Media,” J. Phys Chem. 1957, 61, 1661-1665.

1958
Holm, R. H.; Cotton, F. A.  "Spectral Investigations of Metal Complexes of β-Diketones.  I. Nuclear Magnetic Resonance and Ultraviolet Spectra of Acetylacetonates,” J. Am. Chem. Soc. 1958, 80, 5658-5663.

1959
Cotton, F. A.; Bannister, E.; Barnes, R.; Holm, R. H.  "New Tetrahedral Cations with Phosphine Oxide Ligands,” Proc. Chem. Soc. 1959, 158.

Holm, R. H.; Cotton, F. A.  "Magnetic Investigations of Spin-Free Cobaltous Complexes.  I. Tetrahalo Ions,” J. Chem. Phys. 1959, 31, 788-792.

1960
Holm, R. H.; Cotton, F. A.  "Magnetic Investigations of Spin-Free Cobaltous Complexes. II. Tetrahedral Complexes,” J. Chem. Phys. 1960, 32, 1168-1172.

Cotton, F. A.; Holm, R. H. "Magnetic Investigations of Spin-Free Cobaltous Complexes. III. On the Existence of Planar Complexes,” J. Am. Chem. Soc. 1960, 82, 2979-2983.

Cotton, F. A.; Holm, R. H.  "Magnetic Evidence Indicative of Structures and Structural Changes in Complexes of Cobalt(II),” J. Am. Chem. Soc. 1960, 82, 2983-2986.

Holm, R. H.; Cotton, F. A.  "Dipole Moments and Structures of Some Bis(Trifluoro-acetylacetonato) Complexes,” J. Inorg. Nucl. Chem. 1960, 15, 63-66.

Holm, R. H.; McKinney, T. M. "Magnetic Observations on Some Substituted Nickel(II) Salicylaldimine Complexes,” J. Am. Chem. Soc. 1960, 82, 5506.

Holm, R. H.  "Studies on Nickel(II) Complexes.  I. Spectra of Tricyclic Schiff Base Complexes of Copper(II) and Nickel(II),” J. Am. Chem. Soc. 1960, 82, 5632-5636.

1961
Holm, R. H.; Cotton, F. A. "X-Ray Powder Data and Structures of Some Bis(Acetylacetonato) Metal(II) Complexes and Their Dihydrates,” J. Phys. Chem. 1961, 65, 321-323.

Cotton, F. A.; Goodgame, D. M. L.; Faut, O. D.; Holm, R. H. "Magnetic Investigations of Spin-Free Cobaltous Complexes.  VI. Some Phosphine-Containing Complexes and the Position of Phosphines in the Spectrochemical Series,” J. Am. Chem. Soc. 1961, 83, 1780-1785.

Dudek, G. O.; Holm, R. H.  "A Proton Resonance Study of Bis(Acetylacetone)-ethylenediimine and Related Schiff Bases,” J. Am. Chem. Soc. 1961, 83, 2099-2104.

Holm, R. H.  "Spectral and Magnetic Studies of Substituted Nickel(II) Salicylaldimine Complexes,” in Advances in the Chemistry of Coordination Compounds; Kirschner, S., Ed.; MacMillan: New York, 1961, pp. 341-349.

Dudek, G. O.; Holm, R. H.  "A Nuclear Magnetic Resonance Study of Keto-Enol Equilibria in Schiff Bases. II.,” J. Am. Chem. Soc. 1961, 83, 3914.

Holm, R. H.  "Studies on Nickel(II) Complexes. II. On the Solution Magnetism of Bis(N-methylsalicylaldimine)nickel(II) and Related Complexes,” J. Am. Chem. Soc. 1961, 83, 4683-4690.

1962
Dudek, G. O.; Holm, R. H.  "Nuclear Magnetic Resonance Studies of Keto-Enol Equilibria. III. α,β-Unsaturated β-Ketoamines,” J. Am. Chem. Soc. 1962, 84, 2691-2696.

Holm, R. H.; Swaminathan, K.  "Studies on Nickel(II) Complexes. III. Bis(N-arylsalicyl-aldimine) Complexes,” Inorg. Chem. 1962, 1, 599-607.

1963
Holm, R. H.; Swaminathan, K.  "Studies on Nickel(II) Complexes. IV. Bis(N-sec-alkylsalicylaldimine) Complexes:  Conformational Equilibria in Solution,” Inorg. Chem. 1963, 2, 181-186.

Holm, R. H.; King, R. B.; Stone, F. G. A.  "Nature of the Reaction Product from Cyclopentadienylvanadium Tetracarbonyl and Dimethyl Disulfide,” Inorg. Chem. 1963, 2, 219-220.

Holm, R. H.; Chakravorty, A.; Dudek, G. O.  "Proton Contact Shifts in Dynamical Nickel(II) Complexes and the Detection of Diastereoisomers by Nuclear Resonance,” J. Am. Chem. Soc. 1963, 85, 821-822.

Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H.  "E.s.r. Studies of Four-Coordinate Complexes of Nickel, Palladium, and Platinum Related by Electron Transfer Reactions,” J. Am. Chem. Soc. 1963, 85, 2029-2030.

Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H. "Concerning the Existence of High-Spin Planar Cobaltous Complexes: Bis(1,2-dicyanomaleonitriledithiolato)cobalt(II) Dianion,” J. Am. Chem. Soc. 1963, 85, 3049-3050.

Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H. "The Preparation and Characterization of Four-Coordinate Complexes Related by Electron Transfer Reactions,” Inorg. Chem. 1963, 2, 1227-1232.

1964
Holm, R. H.; Chakravorty, A.; Dudek, G. O.  "Studies on Nickel(II) Complexes. V. A Nuclear Resonance Study of Conformational Equilibria,” J. Am. Chem. Soc. 1964, 86, 379-387.

Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H. "Further Examples of Complexes Related by Electron Transfer Reactions: Complexes Derived from Bis(trifluoromethyl)-1,2-dithietene,” Inorg. Chem. 1964, 3, 814-823.

Chakravorty, A.; Holm, R. H. "Studies on Nickel(II) Complexes. VI. The Conformational Equilibria of Bis(o-Hydroxynaphthaldimine) Complexes,” Inorg. Chem. 1964, 3, 1010-1015.

Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H.  "Synthetic and Electron Spin Resonance Studies of Six-Coordinate Complexes Related by Electron Transfer Reactions,” J. Am. Chem. Soc. 1964, 86, 2799-2805.

Everett, G. W., Jr.; Holm, R. H.  "The Synthesis and Solution Equilibria of Bis(β-Ketoamine)nickel(II) Complexes,” Proc. Chem. Soc. 1964, 238-239.

Chakravorty, A.; Holm, R. H.  "Studies of Nickel(II) Complexes. VII. A Nuclear Resonance Investigation of Mixed Ligand Complexes,” J. Am. Chem. Soc. 1964, 86, 3999-4004.

Enemark, J. H.; Holm, R. H.  "A Study of Transition Metal Compounds Containing the Tricyanomethanide Ion,” Inorg. Chem. 1964, 3, 1516-1521.

Chakravorty, A.; Holm, R. H.  "The Identification of the Geometrical Isomers of Some Tris-Chelate Cobalt(III) Complexes by Nuclear Resonance,” Inorg. Chem. 1964, 3, 1521-1524.
 
Maki, A. H.; Edelstein, N.; Davison, A.; Holm, R. H.  "Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes,” J. Am. Chem. Soc. 1964, 86, 4580-4587.

1965
Chakravorty, A.; Fennessey, J. P.; Holm, R. H.  "Structural Interconversions of Octahedral, Planar, and Tetrahedral Nickel(II) Complexes,” Inorg. Chem. 1965, 4, 26-33.

Davison, A.; Edelstein, N.; Holm, R. H.; Maki, A. H.  "Synthetic and Paramagnetic Resonance Studies of Trigonal Vanadium Complexes,” Inorg. Chem. 1965, 4, 55-59.

Everett, G. W., Jr.; Holm, R. H.  "The Synthesis and Proton Resonance Study of the Solution Equilibria of Bis(β-ketoamino)nickel(II) Complexes,” J. Am. Chem. Soc. 1965, 87, 2117-2127.

Balch, A. L.; Röhrscheid, F.; Holm, R. H.  "New Systems of Complexes Related by Electron Transfer Reactions,” J. Am. Chem. Soc. 1965, 87, 2301-2302.

Röhrscheid, F.; Holm, R. H.  "Zero-valent Nickel Complexes of o-Carboranes,” J. Organometal. Chem. 1965, 4, 335-338.

Everett, G. W., Jr.; Holm, R. H.  "Existence of the Planar-Tetrahedral Equilibrium in Solutions of Cobalt(II) Complexes,” J. Am. Chem. Soc. 1965, 87, 5266-5267.

1966
Holm, R. H.; Everett, G. W., Jr.; Horrocks, W. D., Jr. "Isotropic P.M.R. Shifts in Tetrahedral bis-Pyridine and bis-Picoline Complexes of Nickel(II),” J. Am. Chem. Soc. 1966, 88, 1071-1073.

Maki, A. H.; Berry, T. E.; Davison, A.; Holm, R. H.; Balch, A. L.  "Concerning Cation-Stabilized Free Radicals,” J. Am. Chem. Soc. 1966, 88, 1080-1082.

Holm, R. H.; Chakravorty, A.; Theriot, L. J.  "The Synthesis, Structures, and Solution Equilibria of Bis(pyrrole-2-aldimino)metal(II) Complexes,” Inorg. Chem. 1966, 5, 625-635.

Everett, G. W., Jr.; Holm, R. H.  "Studies of the Planar-Tetrahedral Configurational Equilibrium of Bis(β-Ketoamino) Cobalt(II) Complexes,” J. Am. Chem. Soc. 1966, 88, 2442-2451.

Holm, R. H.; Everett, G. W., Jr.; Chakravorty, A.  "Metal Complexes of Schiff Bases and β-Ketoamines,” Prog. Inorg. Chem. 1966, 7, 83-214.
 
Balch, A. L.; Holm, R. H.  "Electron Transfer Behavior of Dimeric Complexes of Cobalt and Iron with Dithiolate Ligands,” Chem. Commun. 1966, 552-553.

Röhrscheid, F.; Balch, A. L.; Holm, R. H.  "Potential Electron Transfer Complexes of the [M-O4] Type:  Synthesis and Properties of Complexes Derived from Pyrocatechol and Tetachloropyrocatechol,” Inorg. Chem. 1966, 5, 1542-1551.

Balch, A. L.; Holm, R. H.  "Complete Electron Transfer Series of the [M-N4] Type,” J. Am. Chem. Soc. 1966, 88, 5201-5208.

1967
Holm, R. H.; Balch, A. L.; Davison, A.; Maki, A. H.; Berry, T. E.  "Electron Transfer Complexes of the [M-N2S2] Type.  The Existence of Cation-Stabilized Free Radicals,” J. Am. Chem. Soc. 1967, 89, 2866-2874.

Röhrscheid, F.; Ernst, R. E.; Holm, R. H.  "Nuclear Resonance Studies of Vanadium(III) Complexes.  I. Stereochemistry and Electron Delocalization of Tris(β-diketonates),” Inorg. Chem. 1967, 6, 1315-1320.

Röhrscheid, F.; Ernst, R. E.; Holm, R. H. "Nuclear Resonance Studies of Vanadium(III) Complexes. II. Synthesis, Stereochemistry, and Electron Delocalization Properties of Tris(β-Ketoamines),” Inorg. Chem. 1967, 6, 1607-1613.

Davison, A.; Holm, R. H.  "Metal Complexes Derived from cis-1,2-Dicyano-ethylene-1,2-Dithiolate and Bis-Perfluoromethyl-1,2-Dithietene,” Inorg. Syn. 1967, 10, 8-26.

Gansow, O. A.; Olcott, R. J.; Holm, R. H.  "Utility of the Electron Transfer Series Concept.  Deprotonated Complexes of Butane-2,3-dione-bis(2'-Pyridyl-hydrazone),” J. Am. Chem. Soc. 1967, 89, 5470-5471.

Ernst, R. E.; O'Connor, M. J.; Holm, R. H.  "Diastereoisomeric Four-Coordinate Complexes. III. Paramagnetic Nickel(II) Complexes with Three Asymmetric Centers,” J. Am. Chem. Soc. 1967, 89, 6104-6113.

Röhrscheid, F.; Ernst, R. E.; Holm, R. H. "Nuclear Resonance Studies of Vanadium(III) Complexes. III. Synthesis, Stereochemistry, and Electron Delocalization Properties of Tris-Salicylaldehydes and -Salicylaldimines,” J. Am. Chem. Soc. 1967, 89, 6472-6477.

1968
Balch, A. L.; Dance, I. G.; Holm, R. H.  "The Characterization of Dimeric Dithiolene Complexes,” J. Am. Chem. Soc. 1968, 90, 1139-1145.

 O'Connor, M. J.; Ernst, R. E.; Schoenborn, J. E.; Holm, R. H. "Diastereoisomeric Four-Coordinate Complexes. IV. Zinc(II) Complexes with Three Asymmetric Centers and Ligand Racemization in Bis[(N-alkoxycarbonylalkyl)salicylaldimino]-metal(II) Complexes,” J. Am. Chem. Soc. 1968, 90, 1744-1752.

Everett, G. W., Jr.; Holm, R. H.  "Comparative Stereochemical Populations and Thermodynamics of Structural Interconversions of Planar and Tetrahedral Cobalt(II) and Nickel(II) Complexes,” Inorg. Chem. 1968, 7, 776-785.

Holm, R. H.; Röhrscheid, F.; Everett, G. W., Jr.  "Vanadium(III), Cobalt(II), and Nickel(II) β-Ketoamine Complexes,” Inorg. Syn. 1968, 11, 72-82.

Gansow, O. A.; Holm, R. H. "Aqueous Solution Equilibria of Pyridoxamine, Pyridoxal, 3-Hydroxypyridine-2-aldehyde, and 3-Hydroxypyridine-4-aldehyde as Studied by Proton Resonance,” Tetrahedron 1968, 24, 4477-4487.

Parks, J. E.; Holm, R. H.  "The Synthesis, Solution Stereochemistry, and Electron Delocalization Properties of Bis-(β-Iminoamino)nickel(II) Complexes,” Inorg. Chem. 1968, 7, 1408-1416.

Holm, R. H.; Gerlach, D. H.; Gordon, J. G., II; McNamee, M. G. "Comparative Stereochemical Effects of Sulfur and Oxygen Donor Atoms in Four- and Six- Coordinate Metal Complexes,” J. Am. Chem. Soc. 1968, 90, 4184-4185.

O'Connor, M. J.; Ernst, R. E.; Holm, R. H. "Diastereoisomeric Four-Coordinate Complexes. V. Pseudo-Tetrahedral Complexes of Controlled Absolute Configuration. Configurational Interconversion of Nickel(II) Complexes without Racemization,” J. Am. Chem. Soc. 1968, 90, 4561-4568.

Ernst, R. E.; O'Connor, M. J.; Holm, R. H. "Diastereoisomeric Four-Coordinate Complexes. VII. Proton Resonance Detection of the Non-Equivalence of Enantiomeric Nickel(II) Complexes in an Optically Active Solvent,” J. Am. Chem. Soc. 1968, 90, 5305-5306.

Gansow, O. A.; Holm, R. H. "Detection and Identification of Intermediates and Products of a Nonenzymatic Transamination Reaction by Proton Resonance,” J. Am. Chem. Soc. 1968, 90, 5629-5631.

Ernst, R. E.; O'Connor, M. J.; Holm, R. H. "Diastereoisomeric Four-Coordinate Complexes.  VI. Paramagnetic Nickel(II) Complexes with Four Asymmetric Ligand Centers,” J. Am. Chem. Soc. 1968, 90, 5735-5744.

Forbes, C. E.; Holm, R. H.  "Dithiotropolone (2-Mercaptocycloheptatrienethione) and Its Metal Complexes,” J. Am. Chem. Soc. 1968, 90, 6884-6885.
 
1969
Gansow, O. A.; Holm, R. H. "Equilibria and Solute Structures in the Aqueous Systems Pyridoxal-Alanine-Zinc(II) and -Aluminum(III) as Investigated by Proton Resonance,” J. Am. Chem. Soc. 1969, 91, 573-581.

Gerlach, D. H.; Holm, R. H.  "The Relative Stereochemical and Electronic Effects of Oxygen and Sulfur Donor Atoms in Planar and Tetrahedral Complexes of Nickel(II),” J. Am. Chem. Soc. 1969, 91, 3457-3467.

Holm, R. H.  "Applications of Isotropic Shifts to the Investigation of Structures and Structural Equilibria of Metal Complexes,” Acc. Chem. Res. 1969, 2, 307-316.

Olcott, R. J.; Holm, R. H.  "The Crystal and Molecular Structure of the Electron Transfer Complex Butane-2,3-Dione-Bis(2'-Pyridylhydrazonato)Nickel, [Ni(BDPH)-2H],” Inorg. Chim. Acta 1969, 3, 431-437.

Gansow, O. A.; Holm, R. H. "A Proton Resonance Investigation of the Equilibria, Solute Structures, and Transamination in the Aqueous Systems Pyridoxamine-Pyruvate-Zinc(II) and -Aluminum(III),” J. Am. Chem. Soc. 1969, 91, 5984-5993.

Gerlach, D. H.; Holm, R. H. "Preparation and Stereochemistry of Bis-Chelate Chromium(II), Manganese(II), Iron(II), and Cobalt(II) Complexes of the Types M-O4 and M-O2S2,” Inorg. Chem. 1969, 8, 2292-2297.

1970
Gerlach, D. H.; Holm, R. H.  "The Solution Stereochemistry of Four-Coordinate Bis-Chelate Metal(II) Complexes. Further Experimental Results and a Summary of Stereochemical Trends,” Inorg. Chem. 1970, 9, 588-594.

Pignolet, L. H.; Holm, R. H.  "Complexes Containing the Fe-S6 Core with Unusual Magnetic, Electrochemical, and Stereochemical Properties,” J. Am. Chem. Soc. 1970, 92, 1791-1793.

Pignolet, L. H.; Horrocks, W. D.; Holm, R. H.  "Thermodynamics and Kinetics of the Planar-Tetrahedral Interconversion of Dihalobis(diarylmethylphosphine)nickel(II) Complexes,” J. Am. Chem. Soc. 1970, 92, 1855-1863.

Forbes, C. E.; Holm, R. H.  "Dithiotropolonates.  II. The Synthesis and Properties of Dithiotropolone and Its Metal(II) Complexes,” J. Am. Chem. Soc. 1970, 92, 2297-2303.

Parks, J. E.; Wagner, B. E.; Holm, R. H. "Three-Dimensional Macrocyclic Encapsulation Reactions. I. Synthesis of Six-Coordinate Complexes with Non-Octahedral Stereochemistry,” J. Am. Chem. Soc. 1970, 92, 3500-3502.
 
Weinstein, G. N.; O'Connor, M. J.; Holm, R. H. "Preparation, Properties, and Racemization Kinetics of Copper(II) Schiff Base-Amino Acid Complexes Related to Vitamin B6 Catalysis,” Inorg. Chem. 1970, 9, 2104-2112.

Gordon, J. G., II; Holm, R. H. "Intramolecular Rearrangements of Tris-Chelate Complexes.  I. General Theory and the Kinetics and Probable Mechanism of the Isomerization and Racemization of Tris(5-methylhexane-2,4-dionato)-cobalt(III),” J. Am. Chem. Soc. 1970, 92, 5319-5332.

1971
Truex, T. J.; Holm, R. H.  "Non-Template Synthesis of an Unsaturated Tetraaza-[14]-Macrocycle and Its Metal(II) Complexes,” J. Am. Chem. Soc. 1971, 93, 285-286.

Pignolet, L. H.; Lewis, R. A.; Holm, R. H. "Synthesis and Stereochemical Rearrangements of Complexes Containing the Fe-S6 Core,” J. Am. Chem. Soc. 1971, 93, 360-371.

Eaton, G. R.; Holm, R. H.  "Binuclear Bridged Dithiolene Complexes of Iron and Cobalt,” Inorg. Chem. 1971, 10, 805-811.

Hutchinson, J. R.; Gordon, J. G., II; Holm, R. H.  "Intramolecular Rearrangement Reactions of Tris-Chelate Complexes.  II. Kinetics and Probable Mechanism of the Isomerization and Racemization of the 'Fast' Complexes Tris(1-phenyl-5-methylhexane-2,4-dionato)-aluminum(III) and -gallium(III),” Inorg. Chem. 1971, 10, 1004-1017.

Holm, R. H.; O'Connor, M. J. "The Stereochemistry of Bis-Chelate Metal(II) Complexes,” Prog. Inorg. Chem. 1971, 14, 241-401.

Eaton, S. S.; Holm, R. H.  "Inversion and Ligand Exchange Kinetics of Tetrahedral Bis-Chelate Complexes of Zinc(II) and Cadmium(II),” Inorg. Chem. 1971, 10, 1446-1452.

Eaton, S. S.; Holm, R. H. "Stereochemically Non-Rigid Cobalt(III) Complexes,” J. Am. Chem. Soc. 1971, 93, 4913-4914.

Gordon, J. G., II; O'Connor, M. J.; Holm, R. H. "Stereochemistry and Rearrangement Reactions of Some Tris(β-diketonato)- and Tris(β-thioketonato)-metal(III) Complexes,” Inorg. Chim. Acta 1971, 5, 381-391.

Parks, J. E.; Wagner, B. E.; Holm, R. H. "Three-Dimensional Macrocyclic Encapsulation Reactions.  II. Synthesis and Properties of Nonoctahedral Clathro Chelates Derived from Tris(2-aldoximo-6-pyridyl)phosphine and Boron Trifluoride or Tetrafluoride,” Inorg. Chem. 1971, 10, 2472-2478.

Forbes, C. E.; Gold, A.; Holm, R. H. "Complete Electron Transfer Series of the Pt-N2S2 Type,” Inorg. Chem. 1971, 10, 2479-2485.

 Eaton, S. S.; Eaton, G. R.; Holm, R. H.  "Lability of Ruthenium(II) Carbonyl Porphine with Nitrogen Bases,” J. Organometal. Chem. 1971, 32, C52-C54.

Holm, R. H.; Abbott, E. H.  "Applications of Nuclear Magnetic Resonance to Investigations of Structures and Bonding in Coordination Compounds,” in Coordination Chemistry; Martell, A. E., Ed.; Vol. 1; Van Nostrand Reinhold Company: New York, 1971, Chapter 5.

1972
Pignolet, L. H.; Lewis, R. A.; Holm, R. H.  "Synthesis and Stereochemistry of Bis(N,N-disubstituted-dithiocarbamato)maleonitriledithioleneiron Complexes,” Inorg. Chem. 1972, 11, 99-104.

Baldwin, J. E.; Holm, R. H.; Harper, R. W.; Huff, J.; Koch, S.; Truex, T. J.  "The Structure of Dihydrooctaaza-[14]-annulenes and Their Nickel(II) Complexes,” Inorg. Nucl. Chem. Lett. 1972, 8, 393-398.

Herskovitz, T.; Forbes, C. E.; Holm, R. H.  "Dithiotropolonates. III. Ring-Alkylation Reactions of Bis(dithiotropolonato)nickel(II) and -zinc(II) Complexes,” Inorg. Chem. 1972, 11, 1318-1323.

Eaton, S. S.; Eaton, G. R.; Holm, R. H.  "Inter- and Intramolecular Ligand Exchange Reactions of Ruthenium(II) Carbonyl Porphine Complexes with Nitrogen Bases,” J. Organometal. Chem. 1972, 39, 179-195.

Truex, T. J.; Holm, R. H.  "Synthesis and Properties of Tetraaza[14]tetraene and Tetraaza-[14]hexaene Macrocyclic Complexes,” J. Am. Chem. Soc. 1972, 94, 4529-4538.

Patterson, G. S.; Holm, R. H. "Effects of Chelate Ring Substituents on the Polarographic Redox Potentials of Tris(β-diketonato)ruthenium(II,III) Complexes,” Inorg. Chem. 1972, 11, 2285-2288.

Eaton, S. S.; Hutchinson, J. R.; Holm, R. H.; Muetterties, E. L. "Intramolecular Rearrangement Reactions of Tris-Chelate Complexes. III. Analysis of the Rearrangements of Tris(α-isopropenyl- and α-isopropyltropolonato)-aluminum(III) and -cobalt(III).  Examples of Stereochemically Nonrigid Aluminum(III) and Cobalt(III) Complexes,” J. Am. Chem. Soc. 1972, 94, 6411-6426.

Herskovitz, T.; Averill, B. A.; Holm, R. H.; Ibers, J. A.; Phillips, W. D.; Weiher, J. F.  "Structure and Properties of a Synthetic Analogue of Bacterial Iron-Sulfur Proteins,” Proc. Nat. Acad. Sci. USA 1972, 69, 2437-2441.

Weinstein, G. N.; Holm, R. H.  "Synthesis of Tautomeric Schiff Base Complexes and Ketimine → Aldimine Conversion Rates of Copper(II) Complexes,” Inorg. Chem. 1972, 11, 2553-2556.

Larsen, E.; La Mar, G. N.; Wagner, B. E.; Parks, J. E.; Holm, R. H. "Three-Dimensional Macrocyclic Encapsulation Reactions.  III. Geometrical and Electronic Features of Tris(diimine) Complexes of Trigonal Prismatic, Antiprismatic, and Intermediate Stereochemistry,” Inorg. Chem. 1972, 11, 2652-2668.

1973
La Mar, G. N.; Eaton, G. R.; Holm, R. H.; Walker, F. A.  "PMR Investigation of Antiferromagnetic Oxo-Bridged Ferric Dimers and Related High-Spin Monomeric Ferric Complexes,” J. Am. Chem. Soc. 1973, 95, 63-75.

Tang, S. C.; Weinstein, G. N.; Holm, R. H.  "General Synthetic Routes to Tetraaza Macrocycles:  Preparation of the Corrin Inner Ring Structure,” J. Am. Chem. Soc. 1973, 95, 613-614.

Eaton, S. S.; Eaton, G. R.; Holm, R. H.; Muetterties, E. L. "Intramolecular Rearrangement Reactions of Trischelate Complexes. IV. Further Investigation of the Rearrangements of Tris(α-Isopropenyl- and α-Isopropyltropolonato)-metal(III,IV) Complexes,” J. Am. Chem. Soc. 1973, 95, 1116-1124.

Bonnet, J. J.; Eaton, S. S.; Eaton, G. R.; Holm, R. H.; Ibers, J. A.  "Spectroscopic and Structural Characterization of Ruthenium(II) Carbonyl Porphine Complexes,” J. Am. Chem. Soc. 1973, 95, 2141-2149.

Averill, B. A.; Herskovitz, T.; Holm, R. H.; Ibers, J. A.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.  II. Synthesis and Structure of Tetra[mercapto-μ3-sulfidoiron] Clusters, [Fe4S4(SR)4]2-,” J. Am. Chem. Soc. 1973, 95, 3523-3534.

Mayerle, J. J.; Frankel, R. B.; Holm, R. H.; Ibers, J. A.; Phillips, W. D.; Weiher, J. F.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.  III. Structure and Properties of Bis[o-xylyldithiolato-μ2-sulfidoferrate(III)], an Analogue of the 2Fe-2S Proteins,” Proc. Nat. Acad. Sci. USA 1973, 70, 2429-2433.

Parks, J. E.; Wagner, B. E.; Holm, R. H.  "Syntheses Employing Pyridyllithium Reagents.  New Routes to 2,6-Disubstituted Pyridines and 6,6'-Disubstituted 2,2'-Bipyridyls,” J. Organometal. Chem. 1973, 56, 53-66.

Holm, R. H.  "Vitamin B6 Complexes,” in Inorganic Biochemistry; Eichhorn, G., Ed.; Elsevier Publishing Company: Amsterdam, 1973, Chapter 31.

Tang, S. C.; Koch, S.; Weinstein, G. N.; Lane, R. W.; Holm, R. H.  "Synthetic Approaches to 14-, 15- and 16-Membered Tetraaza Macrocycles and Their Metal Complexes,” Inorg. Chem. 1973, 12, 2589-2595.

Holm, R. H.; Hawkins, C. J. "Stereochemistry and Structural and Electronic Equilibria,” in NMR of Paramagnetic Molecules:  Principles and Applications; La Mar, G. N.; Horrocks, W. D.; Holm, R. H. Eds.; Academic Press: New York, 1973, Chapter 7.

McDonald, C. C.; Phillips, W. D.; Lovenberg, W.; Holm, R. H. "PMR Studies on Clostridium pasteurianum Ferredoxin: Origin of the Contact-Shifted Resonances and Denaturation by Dimethylsulfoxide,” Ann. N. Y. Acad. Sci. 1973, 222, 789-799.

1974
Bobrik, M. A.; Que, L., Jr.; Holm, R. H.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins. IV. Ligand Substitution Reactions of the Tetranuclear Clusters [Fe4S4(SR)4]2-,” J. Am. Chem. Soc. 1974, 96, 285-287.

Holm, R. H.; Phillips, W. D.; Averill, B. A.; Mayerle, J. J.; Herskovitz, T.  Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins. V. Proton Resonance Properties of the Tetranuclear Clusters [Fe4S4(SR)4]2-: Evidence for Dominant Contact Interactions,” J. Am. Chem. Soc. 1974, 96, 2109-2117.

Holm, R. H.; Averill, B. A.; Herskovitz, T.; Frankel, R. B.; Gray, H. B.; Siiman, O.; Grunthaner, F. J.  "Equivalence of Metal Centers in the Iron-Sulfur Protein Active Site Analogues [Fe4S4(SR)4]2-,” J. Am. Chem. Soc. 1974, 96, 2644-2646.

Pignolet, L. H.; Patterson, G. S.; Weiher, J. F.; Holm, R. H.  "Magnetic and Mössbauer Properties of Bis(N,N-disubstituted dithiocarbamato)dithioleneiron Complexes,” Inorg. Chem. 1974, 13, 1263-1268.

DePamphilis, B. V.; Averill, B. A.; Herskovitz, T.; Que, L., Jr.; Holm, R. H.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins. VI. Spectral and Redox Characteristics of the Tetranuclear Clusters [Fe4S4(SR)4]2-,” J. Am. Chem. Soc. 1974, 96, 4159-4167.

Que, L., Jr.; Bobrik, M. A.; Ibers, J. A.; Holm, R. H. "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.  VII. Ligand Substitution Reactions of the Tetranuclear Clusters [Fe4S4(SR)4]2- and the Structure of [(CH3)4N]2[Fe4S4(SC6H5)4],” J. Am. Chem. Soc. 1974, 96, 4168-4178.

Frankel, R. B.; Herskovitz, T.; Averill, B. A.; Holm, R. H.; Krusic, P. J.; Phillips, W. D.  "Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. VIII. Some Electronic Properties of [Fe4S4(SR)4]3-, Analogs of the Reduced Bacterial Ferredoxins,” Biochem. Biophys. Res. Commun. 1974, 58, 974-982.

Que, L.; Jr.; Anglin, J. R.; Bobrik, M. A.; Davison, A.; Holm, R. H. "Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins.  IX. Formation and Some Electronic and Reactivity Properties of Fe4S4 Glycyl-L-cysteinylglycyl Oligopeptide Complexes Obtained by Ligand Substitution Reactions,” J. Am. Chem. Soc. 1974, 96, 6042-6048.

Frankel, R. B.; Averill, B. A.; Holm, R. H. "Mössbauer Properties of Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins,” J. Phys. (Paris) 1974, 35, C6 107-112.

1975
Holm, R. H.  "Iron-Sulfur Clusters in Natural and Synthetic Systems,” Endeavour 1975, 34, 38-43.

Que, L., Jr.; Holm, R. H.; Mortenson, L. E.  "Extrusion of Fe2S*2 and Fe4S*4 Cores from the Active Sites of Ferredoxin Proteins,” J. Am. Chem. Soc. 1975, 97, 463-464.

Tang, S. P.-W.; Spiro, T. G.; Antanaitis, C.; Moss, T. H.; Holm, R. H.; Herskovitz, T.; Mortenson, L. E. "Resonance Raman Spectroscopic Evidence for Structural Variation Among Ferredoxin, HiPIP, and [Fe4S4(SCH2Ph)4]2-,” Biochem. Biophys. Res. Commun. 1975, 62, 1-6.

Dukes, G. R.; Holm, R. H.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins. X. Kinetics and Mechanism of the Ligand Substitution Reactions of Arylthiols with the Tetranuclear Clusters [Fe4S4(SR)4]2-,” J. Am. Chem. Soc. 1975, 97, 528-533.

Koch, S.; Tang, S. C.; Holm, R. H.; Frankel, R. B.  "The [Fe(III)N4(SR)] Coordination Unit. Synthesis and Ground State Electronic Properties of Macrocyclic Ferric Thiolates,” J. Am. Chem. Soc. 1975, 97, 914-916.

Koch, S.; Tang, S. C.; Holm, R. H.; Frankel, R. B.; Ibers, J. A. "Ferric Porphyrin Thiolates.  Possible Relationship to Cytochrome P-450 Enzymes and the Structure of (p-Nitrobenzenethiolato)iron(III) Protoporphyrin IX Dimethyl Ester,” J. Am. Chem. Soc. 1975, 97, 916-918.

Mayerle, J. J.; Denmark, S. E.; DePamphilis, B. V.; Ibers, J. A.; Holm, R. H.  "Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. XI. Synthesis and Properties of Complexes Containing the Fe2S2 Core and the Structures of Bis[o-xylyl-α,α'-dithiolato-μ-sulfidoferrate(III)] and Bis-[p-tolylthiolato-μ-sulfidoferrate(III)] Dianions,” J. Am. Chem. Soc. 1975, 97, 1032-1045.

Millar, M.; Holm, R. H.  "Electronic Structure of 5,7,12,14-Tetramethyl-1,4,8,11-tetraazacyclotetradeca-2,4,6,9,11,13-hexaenatonickel(II) Cation Radical, the Central Member of a Ligand-Based Electron Transfer Series,” J. Chem. Soc., Chem. Commun. 1975, 169-170.

Patterson, G. S.; Holm, R. H. "Structural and Electronic Effects on the Polarographic Half-Wave Potentials of Copper(II) Chelate Complexes,” Bioinorg. Chem. 1975, 4, 257-275.

Holm, R. H. "Stereochemically Nonrigid Metal Chelate Complexes,” in Dynamic Nuclear Magnetic Resonance Spectroscopy; Jackman, L. M.; Cotton, F. A., Eds.; Academic Press: New York, 1975, Chapter 9.

Herskovitz, T.; DePamphilis, B. V.; Gillum, W. O.; Holm, R. H. "Bis[bis(1,2-ethane-dithiolato)ferrate(III)] Dianion, a μ2-Thiolato Dimer: Synthesis and Properties,” Inorg. Chem. 1975, 14, 1426-1429.

Tang, S. C.; Holm, R. H. "Synthetic Transformations of Tetraaza Macrocyclic Metal Complexes.  Preparation of the Corrinoid and Other Unsaturated Ring Systems by Oxidative Dehydrogenation Reactions of Nickel(II), Copper(II), and Cobalt(II) Macrocycles,” J. Am. Chem. Soc. 1975, 97, 3359-3366.

Lane, R. W.; Ibers, J. A.; Frankel, R. B.; Holm, R. H. "Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins.  XII. Bis(o-xylyldithiolato)ferrate(III) Monoanion, a Structurally Unconstrained Model for the Rubredoxin FeS4 Unit,” Proc. Nat. Acad. Sci. USA 1975, 72, 2868-2872.

Millar, M.; Holm, R. H.  "Ligand-Based Redox Reactions.  Analysis of the Electron Paramagnetic Resonance Spectrum of the [Ni(Me4[14]hexaenatoN4)]+ Cation Radical, the Central Member of a Three-Membered Electron Transfer Series Containing a Tetraaza[14]annulene Ligand System,” J. Am. Chem. Soc. 1975, 97, 6052-6058.

Yang, C. Y.; Johnson, K. H.; Holm, R. H.; Norman, J. G.  "Theoretical Model for the 4-Fe Active Sites in Oxidized Ferredoxin and Reduced High-Potential Proteins.  Electronic Structure of the Analog [Fe4S4(SCH3)4]2-,” J. Am. Chem. Soc. 1975, 97, 6596-6598.

Koch, S.; Holm, R. H.; Frankel, R. B.  "Synthesis and Ground State Electronic Properties of Tetraaza Macrocyclic Iron(II,III) Complexes Containing [14]-, [15]-, and [16]-Membered Rings,” J. Am. Chem. Soc. 1975, 97, 6714-6723.

1976
Tang, S. C.; Koch, S.; Papaefthymiou, G. C.; Foner, S.; Frankel, R. B.; Ibers, J. A.; Holm, R. H.  "Axial Ligation Modes in Iron(III) Porphyrins:  Models for the Oxidized Reaction States of Cyctochrome P-450 Enzymes and the Molecular Structure of Iron(III)-Protoporphyrin IX Dimethyl Ester p-Nitrobenzenethiolate,” J. Am. Chem. Soc. 1976, 98, 2414-2434.

Gillum, W. O.; Frankel, R. B.; Foner, S.; Holm, R. H. "Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins.  XIII. Further Electronic Structural Relationships Between the Analogs [Fe2S2(SR)4]2- and the Active Sites of Oxidized 2Fe-2S* Proteins,” Inorg. Chem. 1976, 15, 1095-1100.

Holm, R. H. "Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins and Enzymes and Their Relevance to Dinitrogen Fixation,” in Proceedings of the 1st International Symposium on Nitrogen Fixation; Newton, W. E.; Nyman, C. J., Eds.; Washington State University Press: Pullman, Washington, 1976, pp. 75-78.

Dawson, J. H.; Holm, R. H.; Trudell, J. R.; Barth, G.; Lindner, R. E.; Bunnenberg, E.; Djerassi, C.; Tang, S. C. "Oxidized Cytochrome P-450. Magnetic Circular Dichroism Evidence for Thiolate Ligation in the Substrate-Bound Form. Implications for the Catalytic Mechanism,” J. Am. Chem. Soc. 1976, 98, 3707-3709.

Holm, R. H.; Tang, S. C.; Koch, S.; Papaefthymiou, G. C.; Foner, S.; Frankel, R. B.; Ibers, J. A.  "Model System Studies of Axial Ligation in the Oxidized Reaction States of Cytochrome P-450 Enzymes,” in Iron and Copper Proteins; Yasunobu, K. T.; Mower, H. F.; Hayaishi, O., Eds.; Plenum Press: New York, 1976, pp. 321-334.

Haberkorn, R. A.; Que, L., Jr.; Gillum, W. O.; Holm, R. H.; Liu, C. S.; Lord, R. C.  "Cadmium-113 Fourier Transform NMR and Raman Spectroscopic Studies of Cadmium(II)-Sulfur Complexes, Including [Cd10(SCH2CH2OH)16]4+,” Inorg. Chem. 1976, 15, 2408-2414.

Peng, S.-M.; Ibers, J. A.; Millar, M.; Holm, R. H. "Crystal and Molecular Structure of [Ni(Me4[14]hexaenatoN4)]2(CF3SO3)2: Conversion of a Metal-Stabilized π-Radical to a Diamagnetic Dimer with a Long Metal-Metal Bond and Eclipsed Macrocyclic Ligands Upon Crystallization,” J. Am. Chem. Soc. 1976, 98, 8037-8041.

Frankel, R. B.; Papaefthymiou, G. C.; Lane, R. W.; Holm, R. H. "Synthetic Analogues of the Active Sites of Oxidized and Reduced Rubredoxins,” J. Phys. (Paris) 1976, 37, C6 165-170.

Papaefthymiou, G. C.; Frankel, R. B.; Foner, S.; Tang, S. C.; Koch, S.; Holm, R. H.  "Model Fe(III) Porphyrin Systems:  Axial Ligation in Oxidized Cytochrome P-450⋅S,” J. Phys. (Paris) 1976, 37, C6 209-215.
 
1977
Holm, R. H.; Ibers, J. A. "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins,” in Iron-Sulfur Proteins; Lovenberg, W., Ed.; Academic Press: New York, 1977, Chapter 7.

Lane, R. W.; Ibers, J. A.; Frankel, R. B.; Papaefthymiou, G. C.; Holm, R. H.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins. 14. Synthesis, Properties, and Structures of Bis(o-xylyl-α,α'-dithiolato)ferrate(II,III), Analogues of Oxidized and Reduced Rubredoxin Sites,” J. Am. Chem. Soc. 1977, 99, 84-98.

Gillum, W. O.; Mortenson, L. E.; Chen, J.-S.; Holm, R. H. "Quantitative Extrusions of the Fe4S4 Cores of the Active Sites of Ferredoxins and the Hydrogenase of Clostridium pasteurianum,” J. Am. Chem. Soc. 1977, 99, 584-595.
 
Hill, C. L.; Steenkamp, D. J.; Holm, R. H.; Singer, T. P. "Identification of the Iron-Sulfur Center in Trimethylamine Dehydrogenase,” Proc. Nat. Acad. Sci. USA 1977, 74, 547-551.

Holm, R. H. "Identification of Active Sites in Iron-Sulfur Proteins,” in Biological Aspects of Inorganic Chemistry; Addison, A. W.; Cullen, W. R.; Dolphin, D.; James, B. R., Eds.; John Wiley & Sons, Inc.: New York, 1977, pp. 71-111.

Lane, R. W.; Wedd, A. G.; Gillum, W. O.; Laskowski, E. J.; Holm, R. H.; Frankel, R. B.; Papaefthymiou, G. C.  "Synthesis and Electronic Properties of the Tetranuclear Trianions [Fe4S4(SR)4]3-, Analogues of the 4-Fe Active Sites of Reduced Ferredoxins,” J. Am. Chem. Soc. 1977, 99, 2350-2352.

Hill, C. L.; Renaud, J.; Holm, R. H.; Mortenson, L. E.  "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins. 15. Comparative Polarographic Potentials of the
[Fe4S4(SR)4]2-,3- and Clostridium pasteurianum Ferredoxin Redox Couples,” J Am. Chem. Soc. 1977, 99, 2549-2557.

Bobrik, M. A.; Hodgson, K. O.; Holm, R. H. "Inorganic Derivatives of Iron-Sulfur-Thiolate Dimers and Tetramers: The Structures of Tetrachloro-μ-disulfido-diferrate(III) and Tetra(chloro-μ3-sulfido-iron) Dianions,” Inorg. Chem. 1977, 16, 1851-1858.

Cambray, J.; Lane, R. W.; Wedd, A. G.; Johnson, R. W.; Holm, R. H. "Chemical and Electrochemical Interrelationships of 1-Fe, 2-Fe, and 4-Fe Analogues of the Active Sites of Iron-Sulfur Proteins,” Inorg. Chem. 1977, 16, 2565-2571.

Holm, R. H.  "Synthetic Approaches to the Active Sites of Iron-Sulfur Proteins,” Accounts Chem. Res. 1977, 10, 427-434.

1978
Wong, G. B.; Bobrik, M. A.; Holm, R. H.  "Inorganic Derivatives of Iron-Sulfide-Thiolate Dimers and Tetramers: Synthesis and Properties of the Halide Series [Fe2S2X4]2- and [Fe4S4X4]2- (X = Cl-, Br-, I-),” Inorg. Chem. 1978, 17, 578-584.

Bobrik, M. A.; Laskowski, E. J.; Johnson, R. W.; Gillum, W. O.; Berg, J. M.; Hodgson, K. O.; Holm, R. H.  "Selenium Substitution in [Fe4S4(SR)4]2-.  Synthesis and Comparative Properties of [Fe4X4(YC6H5)4]2- (X, Y = S, Se) and the Structure of [(CH3)4]2[Fe4Se4(SC6H5)4],” Inorg. Chem. 1978, 17, 1402-1410.

Wolff, T. E.; Berg, J. M.; Warrick, C.; Hodgson, K. O.; Holm, R. H.; Frankel, R. B.  "The Molybdenum-Iron-Sulfur Cluster Complex [Mo2Fe6S9(SC2H5)8]3-, a Synthetic Approach to the Molybdenum Site in Nitrogenase,” J. Am. Chem. Soc. 1978, 100, 4630-4632.

Reynolds, J. G.; Laskowski, E. J.; Holm, R. H. "Proton Magnetic Resonance Properties of the Tetranuclear Clusters [Fe4S4(SR)4]3-, Analogues of the 4-Fe Sites of Reduced Ferredoxins,” J. Am. Chem. Soc. 1978, 100, 5315-5322.

Laskowski, E. J.; Frankel, R. B.; Gillum, W. O.; Papaefthymiou, G. C.; Renaud, J.; Ibers, J. A.; Holm, R. H. "Synthetic Analogues of the 4-Fe Active Sites of Reduced Ferredoxins.  Electronic Properties of the Tetranuclear Trianions [Fe4S4(SR)4]3- and the Structure of [(C2H5)3(CH3)N]3[Fe4S4(SC6H5)4],” J. Am. Chem. Soc. 1978, 100, 5322-5337.

Johnson, R. W.; Holm, R. H. "Reaction Chemistry of the Iron-Sulfur Protein Active Site Analogues [Fe4S4(SR)4]2-. Sequential Thiolate Ligand Substitution Reactions with Electrophiles,” J. Am. Chem. Soc. 1978, 100, 5338-5344.

Orme-Johnson, W. H.; Holm, R. H. "Identification of Iron-Sulfur Clusters in Proteins,” Meth. Enzymol. 1978, 53D, 268-274.

Kurtz, D. M., Jr.; Wong, G. B.; Holm, R. H. "Structural Identification of the Extruded Cores of the Active Centers of Iron-Sulfur Proteins by Fluorine-19 Nuclear Magnetic Resonance Spectroscopy.  Applications to Milk Xanthine Oxidase,” J. Am. Chem. Soc. 1978, 100, 6777-6779.

1979
Wong, G. B.; Kurtz, D. M., Jr.; Holm, R. H.; Mortenson, L. E.; Upchurch, R. G.  "A 19F NMR Method for Identification of Iron-Sulfur Cores Extruded from Active Centers of Proteins, with Applications to Milk Xanthine Oxidase and Iron-Molybdenum Proteins of Nitrogenase,” J. Am. Chem. Soc. 1979, 101, 3078-3090.

Kurtz, D. M., Jr.; Holm, R. H.; Ruzicka, F. J.; Beinert, H.; Coles, C. J.; Singer, T. P.  "The High-Potential Iron-Sulfur Cluster of Aconitase is a Binuclear Iron-Sulfur Cluster,” J. Biol. Chem. 1979, 254, 4967-4969.

Wolff, T. E.; Berg, J. M.; Hodgson, K. O.; Frankel, R. B.; Holm, R. H.  "Synthetic Approaches to the Molybdenum Site in Nitrogenase. Preparation and Structural Properties of the Molybdenum-Iron-Sulfur 'Double-Cubane' Cluster Complexes [Mo2Fe6S8(SC2H5)9]3- and [Mo2Fe6S9(SC2H5)8]3-,” J. Am. Chem. Soc. 1979, 101, 4140-4150.

Berg, J. M.; Hodgson, K. O.; Holm, R. H. "Crystal Structure of [(C2H5)4N]3[Fe4S4(SCH2Ph)4], a Reduced Ferredoxin Site Analogue with a Nontetragonal Fe4S4 Core Structure in the Solid State,” J. Am. Chem. Soc. 1979, 101, 4586-4593.

Coles, C. J.; Holm, R. H.; Kurtz, D. M., Jr.; Orme-Johnson, W. H.; Rawlings, J.; Singer, T. P.; Wong, G. B.  "Characterization of the Iron-Sulfur Centers in Succinate Dehydrogenase,” Proc. Natl. Acad. Sci. USA 1979, 76, 3805-3808.

Wolff, T. E.; Berg, J. M.; Power, P. P.; Hodgson, K. O.; Holm, R. H.; Frankel, R. B.  "Self-Assembly of Molydenum-Iron-Sulfur Clusters as a Synthetic Approach to the Molybdenum Site in Nitrogenase.  Identification of the Major Products Formed by the System FeCl3/MS42-/C2H5SH (M = Mo, W),” J. Am. Chem. Soc. 1979, 101, 5454-5456.
 
Kurtz, D. M.; McMillan, R. S.; Burgess, B. K.; Mortenson, L. E.; Holm, R. H. "Identification of Iron-Sulfur Clusters in the Iron-Molybdenum Proteins of Nitrogenase,” Proc. Natl. Acad. Sci. USA 1979, 76, 4986-4989.

Laskowski, E. J.; Reynolds, J. G.; Frankel, R. B.; Foner, S.; Papaefthymiou, G. C.; Holm, R. H.  "Demonstration of the Generality of the [Fe4S4(SR)4]2- (Compressed D2d)/[Fe4S4(SR)4]3- (Elongated D2d) Structural Change in Electron Transfer Reactions of Ferredoxin 4-Fe Site Analogues. A Model for the Unconstrained Structural Changes in Ferredoxin Proteins,” J. Am. Chem. Soc. 1979, 101, 6562-6570.

McMillan, R. S.; Renaud, J.; Reynolds, J. G.; Holm, R. H.  "Biologically Related Iron-Sulfur Clusters as Reaction Centers.  Reduction of Acetylene to Ethylene in Systems Based on [Fe4S4(SR)4]2-,” J. Inorg. Biochem. 1979, 11, 213-227.

Stolzenberg, A. M.; Spreer, L. O.; Holm, R. H.  "Iron Octaethylisobacteriochlorin, a Model System for the Siroheme Prosthetic Group of Nitrite and Sulfite Reductases,” J. Chem. Soc., Chem. Commun. 1979, 1077-1078.

1980
Stolzenberg, A. M.; Spreer, L. O.; Holm, R. H.  "Octaethylisobacteriochlorin, A Model of the Sirohydrochlorin Ring System of Siroheme Enzymes:  Preparation and Spectroscopic and Electrochemical Properties of the Free Base and Its Zn(II) Complex,” J. Am. Chem. Soc. 1980, 102, 364-370.

Wolff, T. E.; Berg, J. M.; Power, P. P.; Hodgson, K. O.; Holm, R. H.  "Structural Characterization of the Iron-Bridged 'Double-Cubane' Cluster Complexes [Mo2Fe7S8(C2H5)12]3- and [M2Fe7S8(C2H5)12]4- (M = Mo, W) Containing MFe3S4 Cores,” Inorg. Chem. 1980, 19, 430-437.

Papaefthymiou, G. C.; Frankel, R. B.; Foner, S.; Laskowski, E. J.; Holm, R. H.  "Magnetic Properties of [Fe4S4(SR)4]3- Clusters,” J. Phys. (Paris), Colloq. (C1) 1980, 41, 493-494.

Frankel, R. B.; Wolff, T. E.; Power, P. P.; Holm, R. H.  "Electronic Properties of Molybdenum-Iron-Sulfur Clusters:  Approaches to the Molybdenum Site in Nitrogenase,” J. Phys. (Paris), Colloq. (C1) 1980, 41, 495-496.

Reynolds, J. G.; Coyle, C. L.; Holm, R. H. "Electron Exchange Kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- Systems.  Estimates of the Intrinsic Self-Exchange Rate Constant of 4-Fe Sites in Oxidized and Reduced Ferredoxins,” J. Am. Chem. Soc. 1980, 102, 4350-4355.

Ibers, J. A.; Holm, R. H.  "Modeling Coordination Sites in Metallobiomolecules,” Science 1980, 209, 223-235.
 
Wolff, T. E.; Power, P. P.; Frankel, R. B.; Holm, R. H.  "Synthesis and Electronic and Redox Properties of 'Double-Cubane' Clusters Containing MoFe3S4 and WFe3S4 Cores,” J. Am. Chem. Soc. 1980, 102, 4694-4703.

Hagen, K. S.; Berg, J. M.; Holm, R. H. "The Synthesis and Structure of Deca-(benzenethiolato)tetraferrate(II) Dianion, an Intermediate in the Assembly of [Fe4S4(SC6H5)4]2- from Simple Reagents,” Inorg. Chim. Acta 1980, 45, L17-L18.

Reynolds, J. G.; Holm, R. H. "Improved Synthesis of the Dimeric Complexes [Fe2X2(SC6H4Y)4]2- and [Fe2X2((SCH2)2C6H4)2]2- (X = S, Se), Analogues of the 2-Fe Sites of Oxidized Ferredoxin Proteins,” Inorg. Chem. 1980, 19, 3257-3260.

Christou, G.; Hageman, R. V.; Holm, R. H. "Hydrogen Evolution from Homogeneous Reaction Systems Containing Reduced Mo-Fe-S Clusters,” J. Am. Chem. Soc. 1980, 102, 7600-7601.

1981
Wolff, T. E.; Berg, J. M.; Holm, R. H.  "Synthesis, Structure, and Properties of the Cluster Complex [MoFe4S4(SC2H5)3(C6H4O2)3]3-, Containing a Single Cubane-Type MoFe3S4 Core,” Inorg. Chem. 1981, 20, 174-180.

Paech, C.; Reynolds, J. G.; Singer, T. P.; Holm, R. H. "Structural Identification of Iron-Sulfur Clusters of the Respiratory Chain-linked NADH Dehydrogenase,” J. Biol. Chem. 1981, 256, 3167-3170.

Reynolds, J. G.; Holm, R. H. "Core Chalcogenide Atom Substitution Reactions of [Fe2X2(SR)4]2- and [Fe4X4(SR)4]2-,3- (X = S, Se),” Inorg. Chem. 1981, 20, 1873-1878.

Hagen, K. S.; Reynolds, J. G.; Holm, R. H. "Definition of Reaction Sequences Resulting in Self-Assembly of [Fe4S4(SR)4]2- Clusters,” J. Am. Chem. Soc. 1981, 103, 4054-4063.

Stolzenberg, A. M.; Strauss, S. H.; Holm, R. H. "Iron(II,III)-Chlorin and -Isobacteriochlorin Complexes. Models of the Heme Prosthetic Groups in Nitrite and Sulfite Reductases:  Means of Formation and Spectroscopic and Redox Properties,” J. Am. Chem. Soc. 1981, 103, 4763-4777.

Mascharak, P. K.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H. "Evidence for the Localized Fe(III)/Fe(II) Oxidation State Configuration as an Intrinsic Property of [Fe2S2(SR)4]3- Clusters,” J. Am. Chem. Soc. 1981, 103, 6110-6116.

Armstrong, W. H.; Holm, R. H.  "Synthesis and Structure of a New Type of Mo-Fe-S Double-Cubane Cluster and Evidence for the Formation of Magnetically Uncoupled S = 3/2 MoFe3S4 Subclusters,” J. Am. Chem. Soc. 1981, 103, 6246-6248.
 
Christou, G.; Holm, R. H.; Sabat, M.; Ibers, J. A. "A Hexanuclear Iron-Sulfide-Thiolate Cluster: Assembly and Properties of [Fe6S9(S-t-C4H9)2]4- Containing Three Types of Bridging Sulfur Atoms,” J. Am. Chem. Soc. 1981, 103, 6269-6271.

Holm, R. H. "Metal Clusters in Biology; Quest for a Synthetic Representation of the Catalytic Site of Nitrogenase,” Chem. Soc. Rev. 1981, 10, 455-490.

1982
Palermo, R. E.; Power, P. P.; Holm, R. H. "Ligand Substitution Properties of the MFe3S4 Double-Cubane Cluster Complexes [Mo2Fe6S8(SR)9]3- and [Mo2Fe7S8-(SR)12]3- ( M = Mo, W),” Inorg. Chem. 1982, 21, 173-181.

Strauss, S. H.; Holm, R. H. "Carbon Monoxide Affinities of Iron(II) Octaethylporphyrin, Octaethylchlorin, and Octaethylisobacteriochlorin Complexes,” Inorg. Chem. 1982, 21, 863-868.

Christou, G.; Hagen, K. S.; Holm, R. H.  "Synthesis, Structure, and Properties of [Co8S6(SC6H5)8]4- Containing a Rhombic Dodecahedron Related to That in Cobalt Pentlandite,” J. Am. Chem. Soc. 1982, 104, 1744-1745.

Armstrong, W. H.; Mascharak, P. K.; Holm, R. H.  "Demonstration of the Existence of Single Cubane-Type MoFe3S4 Clusters with S = 3/2 Ground States: Preparation, Structure, and Properties,” Inorg. Chem. 1982, 21, 1699-1701.

Berg, J. M.; Holm, R. H.  "Structures and Reactions of Iron-Sulfur Protein Clusters and Their Synthetic Analogues,” in Iron-Sulfur Proteins; Spiro, T. G., Ed.; John Wiley & Sons, Inc.: New York, 1982, Chapter 1.

Papaefthymiou, G. C.; Laskowski, E. J.; Frota-Pessoa, S.; Frankel, R. B.; Holm, R. H.  "Antiferromagnetic Exchange Interactions in [Fe4S4(SR)4]2-,3- Clusters,” Inorg. Chem. 1982, 21, 1723-1728.

Christou, G.; Mascharak, P. K.; Armstrong, W. H.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H.  "Electron Transfer Series of MoFe3S4 Double-Cubane Clusters:  Electronic Properties of Components and the Structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9],” J. Am. Chem. Soc. 1982, 104, 2820-2831.

Armstrong, W. H.; Mascharak, P. K.; Holm, R. H.  "Doubly-Bridged Double-Cubanes Containing MFe3S4 Clusters (M = Mo, W).  Synthesis, Structure, and Conversion to Spin-Quartet Single Clusters in Solution,” J. Am. Chem. Soc. 1982, 104, 4373-4383.

Christou, G.; Sabat, M.; Ibers, J. A.; Holm, R. H.  "A New Structural Type in Iron-Sulfide-Thiolate Chemistry:  Preparation, Properties, and Structure of the Hexanuclear Cluster [Fe6S9(S-t-C4H9)2]4-,” Inorg. Chem. 1982, 21, 3518-3526.
 
Hagen, K. S.; Holm, R. H.  "Systematic Iron(II)-Thiolate Chemistry: Synthetic Entry to Trinuclear Complexes,” J. Am. Chem. Soc. 1982, 104, 5496-5497.

Hagen, K. S.; Stephan, D. W.; Holm, R. H.  "Metal Ion Exchange Reactions in Cage Molecules: The Systems [M4-nM'n(SC6H5)10]2- (M,M' = Fe(II), Co(II), Zn(II), Cd(II)) with Adamantane-like Stereochemistry and the Structure of [Fe4(SC6H5)10]2-,” Inorg. Chem. 1982, 21, 3928-3936.

Mascharak, P. K.; Smith, M. C.; Armstrong, W. H.; Burgess, B. K.; Holm, R. H.  "Fluorine-19 Chemical Shifts as Structural Probes of Metal-Sulfur Clusters and the Cofactor of Nitrogenase,” Proc. Nat. Acad. Sci. USA 1982, 70, 7056-7060.

Hawkins, C. J.; Holm, R. H.; Palmer, J. A.; Traficante, D. D.  "Conformational Analysis of Coordination Compounds.  XIV. Proton, Carbon-13, Cobalt-59, and Platinum-195 NMR Spectra of Six-Membered Diamine Chelate Rings,” Aust. J. Chem. 1982, 35, 1815-1828.

1983
Hagen, K. S.; Christou, G.; Holm, R. H.  "Trinuclear Metal(II)-Sulfide-Thiolate Complexes:  Synthesis, Structures, and Properties of [M3S(1,2-(SCH2)2C6H4)3]2- (M = Fe(II), Co(II)),” Inorg. Chem. 1983, 22, 309-314.

Mascharak, P. K.; Armstrong, W. H.; Mizobe, Y.; Holm, R. H.  "Single Cubane-Type MFe3S4 Clusters (M = Mo, W):  Synthesis and Properties of Oxidized and Reduced Forms and the Structure of (Et4N)3[MoFe3S4(S-p-C6H4Cl)4(3,6-(C3H5)2-C6H2O2)],” J. Am. Chem. Soc. 1983, 105, 475-483

Holm, R. H.; Armstrong, W. H.; Christou, G.; Mascharak, P. K.; Mizobe, Y.; Palermo, R. E.; Yamamura, T.  "Toward a Model of the Cofactor of Nitrogenase: Recent Developments in the Chemistry of MoFe3S4 Cubane-Type Clusters,” in Biomimetic Chemistry (Proceedings of the 2nd International Kyoto Conference of New Aspects of Organic Chemistry); Yoshida, Z. I.; Ise, N., Eds.; Elsevier Scientific Publishing Co.; New York, 1983, pp. 79-99.

Yamamura, T.; Christou, G.; Holm, R. H. "The Homogeneous Hydrogen-Evolving Systems [Mo2Fe6S8(SPh)9]4-,5-/C6H5SH: Reaction Characteristics, Kinetics, and Possible Mechanisms,” Inorg. Chem. 1983, 22, 939-949.

Stephan, D. W.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H. "Analogues of the [4Fe-4S]+ Sites of Reduced Ferredoxins: Structural and Spectroscopic Properties of [(C2H5)4N]3[Fe4S4(S-p-C6H4Br)4] in Crystalline and Solution Phases,” Inorg. Chem. 1983, 22, 1550-1557.

Berg, J. M.; Holm, R. H. "Structure Proofs of Ligated and Polymeric Dioxo-molybdenum(VI)-Tridentate Complexes:  MoO2(C5H3N-2,6-(CH2S)2)(C4H8SO) and [MoO2(C5H3N-2,6-(CH2O)2)]n,” Inorg. Chem. 1983, 22, 1768-1771.
 
Hagen, K. S.; Watson, A. D.; Holm, R. H. "Synthetic Routes to Fe2S2, Fe3S4, and Fe6S9 Clusters from the Common Precursor [Fe(SC2H5)4]2-: Structures and Properties of [Fe3S4(SR)4]3- and [Fe6S9(SC2H5)2]4-, Examples of the Newest Types of Fe-S-SR Clusters,” J. Am. Chem. Soc. 1983, 105, 3905-3913.

Palermo, R. E.; Holm, R. H.  "Reactivity Properties of Single MoFe3S4 Cubane-Type Clusters: Synthesis, Structure, and Ligand Substitution Reactions of [MoFe3S4Cl3(3,6-(C3H5)2C6H2O2)(THF)]2-,” J. Am. Chem. Soc. 1983, 105, 4310-4318.

Mascharak, P. K.; Hagen, K. S.; Spence, J. T.; Holm, R. H.  "Structural Distortions of the [Fe4S4]2+ Core of [Fe4S4(S-t-C4H9)4]2- in Different Crystalline Environments and Detection and Instability of Oxidized ([Fe4S4]3+) Clusters,” Inorg. Chim. Acta 1983, 80, 157-170.

Mascharak, P. K.; Papaefthymiou, G. C.; Armstrong, W. H.; Foner, S.; Frankel, R. B.; Holm, R. H.  "Electronic Properties of Single- and Double-MoFe3S4 Cubane-Type Clusters,” Inorg. Chem. 1983, 22, 2851-2858.

Hagen, K. S.; Holm, R. H.  "Stereochemistry of [Cd4(SC6H5)10]2-, a Cage Complex Related to the Cadmium-Cysteinate Aggregates in Metallothioneins,” Inorg. Chem. 1983, 22, 3171-3173.

Mizobe, Y.; Mascharak, P. K.; Palermo, R. E.; Holm, R. H.  "Synthesis and Selected Properties of a Reduced Single-Cubane Cluster Containing the [MoFe3S4]2+ (S = 2) Core,” Inorg. Chim. Acta 1983, 80, L65-L67.

Yachandra, V. K.; Hare, J.; Gewirth, A.; Czernuszewicz, R. S.; Kimura, T.; Holm, R. H.; Spiro, T. G. "Resonance Raman Spectra of Spinach Ferredoxin and Adrenodoxin and of Analogue Complexes,” J. Am. Chem. Soc. 1983, 105, 6462-6468.

Dorfman, J. R.; Holm, R. H. "Tetrakis(ethane-1,2-dithiolato)divanadate(III): A Binuclear Complex with a Quadruple Bridge, a Metal-Metal Bond, and Nonoctahedral Stereochemistry,” Inorg. Chem. 1983, 22, 3179-3181.

Do, Y.; Simhon, E. D.; Holm, R. H. "Derivatives of Tetrathiothiovanadate(V): Synthesis of the Linear Heterometallic Fe(μ2-S)2V(μ2-S)2Fe Core and the Structures of [VS4]3- and [VFe2S4Cl4]3-,” J. Am. Chem. Soc. 1983, 105, 6731-6732.

Do, Y.; Simhon, E. D.; Holm, R. H. "Improved Syntheses of [Fe2S2Cl4]2- and [Fe2OCl6]2- and Oxo/Sulfido Ligand Substitution by Use of Silylsulfide Reagents,” Inorg. Chem. 1983, 22, 3809-3812.

Johnson, R. E.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H. "Effects of Secondary Bonding Interactions on the [Fe4S4]2+ Core of Ferredoxin Site Analogues:  [Fe4S4(SC6H4-o-OH)4]2-, a Distorted Cubane-Type Cluster with One Five-Coordinate Iron Atom,” J. Am. Chem. Soc. 1983, 105, 7280-7287.
 
Costa, T.; Dorfman, J. R.; Hagen, K. S.; Holm, R. H. "Synthesis and Stereochemistry of Mono-, Bi- and Tetranuclear Manganese Thiolates,” Inorg. Chem. 1983, 22, 4091-4099.
    
Sola, J.; Do, Y.; Berg, J. M.; Holm, R. H. "Soluble Metal Sulfides: Synthesis and Structure of [M6S17]4- (M = Nb, Ta): Icosahedral-Fragment Cages Containing Four Types of Coordinated Sulfide,” J. Am. Chem. Soc. 1983, 105, 7784-7786.

1984
Holm, R. H.; Hagen, K. S.; Watson, A. D. "Assembly of Biologically Relevant Iron-Sulfur Clusters,” in Chemistry for the Future; Grünewald, H., Ed.; Pergamon Press: New York, 1984, pp. 115-124.

Hagen, K. S.; Holm, R. H. "Synthesis and Stereochemistry of Metal(II) Thiolates of the Types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II)),” Inorg. Chem. 1984, 23, 418-427.

Palermo, R. E.; Singh, R.; Bashkin, J. K.; Holm, R. H. "Molybdenum Atom Substitution Reactions of MoFe3S4 Cubane-Type Clusters: Synthesis and Structures of Clusters Containing Mo-Bound Pseudosubstrates of Nitrogenase,” J. Am. Chem. Soc. 1984, 106, 2600-2612.

Okuno, Y.; Horita, K.; Yonemitsu, O.; Shibata, T.; Amemiya, T.; Holm, R. H. "A Convenient Method for the Synthesis of Macrocyclic Tetraamides by Double Condensation Reaction,” J. Chem. Soc., Perkin Trans. I 1984, 1115-1118.

Berg, J. M.; Holm, R. H. "Synthetic Approach to the Mononuclear Active Sites of Molybdoenzymes: Catalytic Oxygen Atom Transfer Reactions by Oxo-molybdenum(IV,VI) Complexes with Saturation Kinetics and Without Molybdenum(V) Dimer Formation,” J. Am. Chem. Soc. 1984, 106, 3035-3036.

Armstrong, W. H.; Youinou, M.-T.; Palermo, R. E.; Holm, R. H.  "Synthesis of a New Class of Polydentate Ligands: [Bis(2-imidazoyl)methyl]amino-Thioether-Thiols,” Inorg. Chim. Acta 1984, 88, 21-27.

Hagen, K. S.; Watson, A. D.; Holm, R. H.  "Analogues of the [Fe4S4]+ Sites of Reduced Ferredoxins:  Single-Step Synthesis of the Clusters [Fe4S4(SR)4]3- and Examples of Compressed Tetragonal Core Structures,” Inorg. Chem. 1984, 23, 2984-2990.

Girerd, J.-J.; Papaefthymiou, G. C.; Watson, A. D.; Gamp, E.; Hagen, K. S.; Edelstein, N.; Frankel, R. B.; Holm, R. H. "Electronic Properties of the Linear Antiferromagnetically Coupled Clusters [Fe3S4(SR)4]3-, Structural Isomers of the [Fe3S4]+ Unit in Iron-Sulfur Proteins,” J. Am. Chem. Soc. 1984, 106, 5941-5947.

Reynolds, M. S.; Berg, J. M.; Holm, R. H. "Kinetics of Oxygen Atom Transfer Reactions Involving Oxomolybdenum Complexes.  General Treatment for Reactions with Intermediate Oxo-Bridged Molybdenum(V) Dimer Formation,” Inorg. Chem. 1984, 23, 3057-3062.

Holm, R. H.; Berg, J. M.  "Mononuclear Active Sites of Molybdoenzymes: Chemical Approaches to Structure and Reactivity,” Pure Appl. Chem. 1984, 56, 1645-1657.

Dorfman, J. R.; Girerd, J.-J.; Simhon, E. D.; Stack, T. D. P.; Holm, R. H.  "Synthesis, Structure, and Electronic Features of (μ-Sulfido)bis[N,N'-ethylene-bis(salicylaldiminato)iron(III)], [Fe(salen)]2S, Containing the Only Authenticated Example of the Fe(III)-S-Fe(III) Single Bridge,” Inorg. Chem. 1984, 23, 4407-4412.

1985
Berg, J. M.; Holm, R. H. "A Model for the Active Sites of Oxo-Transfer Molybdoenzymes:  Synthesis, Structure, and Properties,” J. Am. Chem. Soc. 1985, 107, 915-925.

Berg, J. M.; Holm, R. H. "A Model for the Active Sites of Oxo-Transfer Molybdoenzymes:  Reactivity, Kinetics, and Catalysis,” J. Am. Chem. Soc. 1985, 107, 925-932.

Dorfman, J. R.; Pulla Rao, Ch.; Holm, R. H. "Structural Diversity of Homoleptic Ethane-1,2-dithiolato Complexes of the First Transition Series,” Inorg. Chem. 1985, 24, 453-454.

Kovacs, J. A.; Bashkin, J. K.; Holm, R. H. "Persulfide-Bridged Iron-Molybdenum-Sulfur Clusters of Biological Relevance:  Two Synthetic Routes and the Structures of Intermediates and Product Clusters,” J. Am. Chem. Soc. 1985, 107, 1784-1786.

Christou, G.; Hagen, K. S.; Bashkin, J. K.; Holm, R. H. "Preparation, Properties, and Structural Relationship of Near-Cubic Co8(μ4-S)6 Cores to the Clusters in Synthetic Pentlandite,” Inorg. Chem. 1985, 24, 1010-1018.

Sola, J.; Do, Y.; Berg, J. M.; Holm, R. H. "Soluble Sulfides of Niobium(V) and Tantalum(V):  Synthesis, Structures, and Properties of the Five-Fold Symmetric Cages [M6S17]4-,” Inorg. Chem. 1985, 24, 1706-1713.

Do, Y.; Simhon, E. D.; Holm, R. H. "Oxo/Sulfido Ligand Substitution in [Mo2O7]2-:  Reaction Sequence and Characterization of the Final Product, [MoS3(OSiMe3)]-,” Inorg. Chem. 1985, 24, 1831-1838.

Watson, A. D.; Pulla Rao, Ch.; Dorfman, J. R.; Holm, R. H. "Systematic Stereochemistry of Metal(II) Thiolates:  Synthesis and Structures of [M2(SC2H5)6]2- (M = Mn(II), Ni(II), Zn(II), Cd(II)),” Inorg. Chem. 1985, 24, 2820-2826.

Do, Y.; Simhon, E. D.; Holm, R. H. "Trinuclear Oxothiomolybdates from the Reductive Cleavage of [Mo8O26]4- with Hexamethyldisilthiane,” Inorg. Chem. 1985, 24, 2827-2832.
 
Do, Y.; Holm, R. H. "Variation of Niobium-Sulfur Multiple Bond Lengths: The Molecular Structure of Sulfidotris(N,N-diethyldithiocarbamato)niobium(V),” Inorg. Chim. Acta 1985, 104, 33-40.

Holm, R. H.; Simhon, E. D. "Molybdenum/Tungsten-Iron-Sulfur Chemistry:  Current Status and Relevance to the Native Cluster of Nitrogenase,” in Molybdenum Enzymes; Spiro, T. G., Ed.; Wiley-Interscience: New York, 1985, Chapter 1.

Do, Y.; Simhon, E. D.; Holm, R. H. "Tetrathiovanadate(V) and Tetrathiorhenate(VII):  Structure and Reactions, Including Characterization of the VFe2S4 Core Unit,” Inorg. Chem. 1985, 24, 4635-4642.

Conradson, S. D.; Burgess, B. K.; Newton, W. E.; Hodgson, K. O.; McDonald, J. W.; Rubinson, J. F.; Gheller, S. F.; Mortenson, L. E.; Adams, M. W. W.; Mascharak, P. K.; Armstrong, W. H.; Holm, R. H.  "Structural Insights from the Mo K-Edge X-Ray Absorption Near-Edge Structure of the Iron-Molybdenum Protein of Nitrogenase and Its Iron-Molybdenum Cofactor by Comparison with Synthetic Fe-Mo-S Clusters,” J. Am. Chem. Soc. 1985, 107, 7935-7940.

1986
Kovacs, J. A.; Holm, R. H. "Assembly of Vanadium-Iron-Sulfur Cubane Clusters from Mononuclear and Linear Trinuclear Reactants,” J. Am. Chem. Soc. 1986, 108, 340-341.

Pulla Rao, Ch.; Dorfman, J. R.; Holm, R. H. "Synthesis and Structural Systematics of Ethane-1,2-dithiolate Complexes,” Inorg. Chem. 1986, 25, 428-439.

Carney, M. J.; Holm, R. H.; Papaefthymiou, G. C.; Frankel, R. B.  "Demonstration of Alternative Spin States of Clusters Containing the Biologically Relevant [Fe4S4]1+ Core,” J. Am. Chem. Soc. 1986, 108, 3519-3521.

Mukherjee, R. N.; Pulla Rao, Ch.; Holm, R. H. "The Solution Chemistry of Ethane-1,2-dithiolate Complexes: Monomer-Dimer Equilibria and Electron Transfer Reactions,” Inorg. Chem. 1986, 25, 2979-2989.

Whitener, M. A.; Bashkin, J. K.; Hagen, K. S.; Girerd, J.-J.; Gamp, E.; Edelstein, N.; Holm, R. H.  "A New Inorganic Ring System:  Planar Fe3(μ2-S)3 in [Fe3(SR)3X6]3- -- Synthesis, Structure, and Solution Conformation and Equilibrium,” J. Am. Chem. Soc. 1986, 108, 5607-5620.

Snyder, B. S.; Pulla Rao, Ch.; Holm, R. H. "Mono- and Binuclear Metal(II) Complexes of Ethane-1,2-dithiolate:  Preparation, Equilibrium, and Redox Properties of [Ni(S2C2H4)2]2- and [Ni2(S2C2H4)3]2- and the Structures of [Ni2(S2C2H4)3]2- and [Pd(S2C2H4)2]2-,” Aust. J. Chem. 1986, 39, 963-974.
 
Noda, I.; Snyder, B. S.; Holm, R. H. "Fe7S6(PEt3)4Cl3: A Topological Link Between the Prismatic and Cube-Octahedral Structures of Iron-Sulfur Clusters,” Inorg. Chem. 1986, 25, 3851-3853.

Harlan, E. W.; Berg, J. M.; Holm, R. H. "Thermodynamic Fitness of Molybdenum(IV,VI) Complexes for Oxygen Atom Transfer Reactions, Including Those with Enzymatic Substrates,” J. Am. Chem. Soc. 1986, 108, 6992-7000.

Holm, R. H.; Berg, J. M. "Analogue Reaction Systems of the Molybdenum Oxo-Transferases,” Accounts Chem. Res. 1986, 19, 363-370.

Caradonna, J. P.; Harlan, E. W.; Holm, R. H. "Thiol as an Electron Donor in Molybdenum Oxo-Transferase Reaction Systems: Observations by 19F NMR Spectroscopy and Biological Implications,” J. Am. Chem. Soc. 1986, 108, 7856-7858.

1987
Zhang, Y.-P.; Bashkin, J. K.; Holm, R. H. "Phosphine Cleavage of Iron(III)-Bridged Double Cubanes:  A New Route to MoFe3S4 Single Cubanes,” Inorg. Chem. 1987, 26, 694-702.

Kovacs, J. A.; Holm, R. H. "Heterometallic Clusters:  Synthesis and Reactions of Vanadium-Iron-Sulfur Single- and Double-Cubane Clusters, and the Structure of [V2Fe6S8Cl4(C2H4S2)2]4-,” Inorg. Chem. 1987, 26, 702-711.

Kovacs, J. A.; Holm, R. H. "Structural Chemistry of Vanadium-Iron-Sulfur Clusters Containing the Cubane-Type [VFe3S4]2+ Core,” Inorg. Chem. 1987, 26, 711-718.

Carney, M. J.; Kovacs, J. A.; Zhang, Y.-P.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H. "Comparative Electronic Properties of Vanadium-Iron-Sulfur and Molybdenum-Iron-Sulfur Clusters Containing the Cubane-Type [VFe3S4]2+ and [MoFe3S4]3+ Cores,” Inorg. Chem. 1987, 26, 719-724.

Stack, T. D. P.; Holm, R. H.  "Subsite-Specific Functionalization of the [4Fe-4S]2+ Analogue of Iron-Sulfur Protein Clusters,” J. Am. Chem. Soc. 1987, 109, 2546-2547.

Kovacs, J. A.; Bashkin, J. K.; Holm, R. H. "[Fe2S2(CO)6]2- as a Cluster Precursor:  Synthesis and Structure of [MoFe3S6(CO)6]2- and Oxidative Decarbonylation to a Persulfide-Bridged MoFe3S4 Double Cubane,” Polyhedron 1987, 6, 1445-1456.

Krüger, H.-J.; Holm, R. H. "Stabilization of Nickel(III) in a Classical N2S2 Coordination Environment Containing Anionic Sulfur,” Inorg. Chem. 1987, 26, 3645-3647.

Holm, R. H.  "Metal-Centered Oxygen Atom Transfer Reactions,” Chem. Rev. 1987, 87, 1401-1449.
 
1988
Carney, M. J.; Whitener, M. A.; Papaefthymiou, G. C.; Frankel, R. B.; Spartalian, K.; Holm, R. H. "Alternative Spin States in Synthetic Analogues of Biological Clusters:  Spin Quartet Ground States and the Structures of [Fe4S4(SPh)4]3- and [Fe4Se4(SPh)4]3- as Their Tetramethylammonium Salts,” Inorg. Chem. 1988, 27, 346-352.

Snyder, B. S.; Reynolds, M. S.; Noda, I.; Holm, R. H.  "Core Conversion Reactions of Iron-Sulfur Clusters: Topological Isomer of the Fe6S6-Prismane Core,” Inorg. Chem. 1988, 27, 595-597.

Mukherjee, R. N.; Stack, T. D. P.; Holm, R. H.  "Angle Dependence of the Properties of the [Fe2X]4+ Bridge Unit (X = O, S):  Structures, Antiferromagnetic Coupling, and Properties in Solution,” J. Am. Chem. Soc. 1988, 110, 1850-1861.

Caradonna, J. P.; Reddy, P. R.; Holm, R. H. "Kinetics, Mechanisms, and Catalysis of Oxygen Atom Transfer Reactions of S-Oxide and Pyridine N-Oxide Substrates with Molybdenum(IV,VI) Complexes: Relevance to Molybdoenzymes,” J. Am. Chem. Soc. 1988, 110, 2139-2144.

Stack, T. D. P.; Holm, R. H. "Subsite-Differentiated Analogues of Biological [4Fe-4S]2+ Clusters:  Synthesis, Solution, and Solid State Structures, and Subsite-Specific Reactions,” J. Am. Chem. Soc. 1988, 110, 2484-2494.

Mukherjee, R. N.; Abrahamson, A. J.; Patterson, G. S.; Stack, T. D. P.; Holm, R. H.  "A New Class of N,N-Bis(salicylideneamino)ethane Iron Complexes: Five-Coordinate [FeII(salen)L]1- -- Preparation, Properties, and Mechanism of Electron Transfer Reactions,” Inorg. Chem. 1988, 27, 2137-2144.

Snyder, B. S.; Holm, R. H. "Hexanuclear Iron-Sulfur Basket Clusters -- Topological Isomers of Prismanes: Synthesis, Structure, and Reactions,” Inorg. Chem. 1988, 27, 2339-2347.

Carney, M. J.; Papaefthymiou, G. C.; Spartalian, K.; Frankel, R. B.; Holm, R. H.  "Ground Spin State Variability in [Fe4S4(SR)4]3-, Synthetic Analogues of the Reduced Clusters in Ferredoxins and other Iron-Sulfur Proteins:  Cases of Extreme Sensitivity of Electronic State and Structure to Extrinsic Factors,” Inorg. Chem. 1988, 27, 6084-6095.

You, J.-F.; Snyder, B. S.; Holm, R. H. "[Na2Fe18S30]8-: A High-Nuclearity Cluster Generated Solely by Iron-Sulfur Bridge Bonding,” J. Am. Chem. Soc. 1988, 110, 6589-6591.

Conradson, S. D.; Burgess, B. K.; Holm, R. H. "Fluorine-19 Chemical Shifts as Probes of the Structure and Reactivity of the Iron-Molybdenum Cofactor of Nitrogenase,” J. Biol. Chem. 1988, 263, 13743-13749.

Zhang, Y.-P.; Holm, R. H. "Li3[VS4]⋅2DMF: A Solubilized Form of Tetrathiovanadate(V),” Inorg. Chem. 1988, 27, 3875-3876.

Reynolds, M. S.; Holm, R. H. "Iron-Sulfur-Thiolate Basket Clusters,” Inorg. Chem. 1988, 27, 4494-4499.

1989
Reynolds, M. S.; Holm, R. H. "Binding of Oxysulfur Anions to Macrocyclic Iron(II,III):  [(Fe(TPP))2SO4] and [Fe(Me6[14]-4,11-dieneN4)(S2O5)],” Inorg. Chim. Acta 1989, 155, 113-123.

Stack, T. D. P.; Carney, M. J.; Holm, R. H. "Formation of Bridged [4Fe-4S]2+ Double Cubanes by Site-Specific Reactions: Electron Transfer Coupling Across Sulfur-Containing Bridges of Variable Length,” J. Am. Chem. Soc. 1989, 111, 1670-1676.

Craig, J. A.; Holm, R. H. "Reduction of Nitrate to Nitrite by Molybdenum-Mediated Atom Transfer: A Nitrate Reductase Analogue Reaction System,” J. Am. Chem. Soc. 1989, 111, 2111-2115.

Krüger, H.-J.; Holm, R. H. "Chemical and Electrochemical Reactivity of Nickel(II,I) Thiolate Complexes:  Examples of Ligand-Based Oxidation and Metal-Centered Oxidative Addition,” Inorg. Chem. 1989, 28, 1148-1155.

Carney, M. J.; Frankel, R. B.; Papaefthymiou, G. C.; Holm, R. H.  "Alternative Spin States in Synthetic Analogues of Biological [4Fe-4S]1+ Clusters:  Further Cases of 'Spin-Admixed' Ground States and the Structure of (Et4N)3[Fe4S4(S-o-C6H4S-t-Bu)4], Containing a Reduced Cluster with a Compressed Tetragonal Distortion,” Inorg. Chem. 1989, 28, 1497-1503.

Ciurli, S.; Holm, R. H. "Insertion of [VFe3S4]2+ and [MoFe3S4]3+ Cores into a Semirigid Trithiolate Cavitand Ligand: Regiospecific Reactions at a Vanadium Site Similar to That in Nitrogenase,” Inorg. Chem. 1989, 28, 1685-1690.

Craig, J. A.; Harlan, E. W.; Snyder, B. S.; Whitener, M. A.; Holm, R. H.  "Oxomolybdenum(IV,V,VI) Complexes: Structures, Reactivities, and Criteria of Detection of Binuclear μ-Oxo Mo(V) Products in Oxygen Atom Transfer Systems,” Inorg. Chem. 1989, 28, 2082-2091.

Snyder, B. S.; Patterson, G. S.; Abrahamson, A. J.; Holm, R. H. "A Binuclear Iron System Ferromagnetic in Three Oxidation States: Synthesis, Structures and Electronic Aspects of Molecules with a Fe2(OR)2 Bridge Unit Containing Fe(III,III), Fe(III,II), and Fe(II,II),” J. Am. Chem. Soc. 1989, 111, 5214-5223.

Surerus, K. K.; Münck, E.; Snyder, B. S.; Holm, R. H. "A Binuclear Mixed-Valence Ferromagnetic Iron System with an S = 9/2 Ground State and Valence Trapped and Detrapped States,” J. Am. Chem. Soc. 1989, 111, 5501-5502.

Ciurli, S.; Carney, M. J.; Papaefthymiou, G. C.; Holm, R. H. "On the Stability Range of Heterometal Cubane-type Clusters MFe3S4: Assembly of Double-Cubane Clusters with the ReFe3S4 Core,” Inorg. Chem. 1989, 28, 2696-2698.

Conradson, S. D.; Burgess, B. K.; Vaughn, S. A.; Roe, A. L.; Hedman, B.; Hodgson, K. O.; Holm, R. H. "Cyanide and Methylisocyanide Binding to the Isolated Iron-Molybdenum Cofactor of Nitrogenase,” J. Biol. Chem. 1989, 264, 15967-15974.

Yu, S.-B.; Holm, R. H. "Aspects of the Oxygen Atom Transfer Chemistry of Tungsten,” Inorg. Chem. 1989, 28, 4385-4391.

Weigel, J. A.; Surerus, K. K.; Münck, E.; Holm, R. H. "Spin-Isolation of the [3Fe-4S] Fragment of a [4Fe-4S] Cluster:  Electronic Properties of the [3Fe-4S]0 Cluster,” J. Am. Chem. Soc. 1989, 112, 9246-9247.

1990
Harlan, E. W.; Holm, R. H. "Molybdenum-Mediated Imido Group Transfer:  Stoichiometric and Catalytic Reactions and Structures,” J. Am. Chem. Soc. 1990, 112, 186-193.

Snyder, B. S.; Holm, R. H. "[Fe6S6(PEt3)6]1+: Extension of Stabilization of the Basket Core Topology to the [Fe6S6]1+ Oxidation Level,” Inorg. Chem. 1990, 29, 274-279.

You, J.-F.; Snyder, B. S.; Papaefthymiou, G. C.; Holm, R. H. "On the Molecular/Solid State Boundary. A Cyclic Iron-Sulfur Cluster of Nuclearity Eighteen: Synthesis, Structure, and Properties,” J. Am. Chem. Soc. 1990, 112, 1067-1076.

Zhang, Y.-P.; Holm, R. H.  "Vanadium-Mediated Oxygen Atom Transfer Reactions,” Inorg. Chem. 1990, 29, 911-917.

Ciurli, S.; Carrié, M.; Weigel, J. A.; Carney, M. J.; Stack, T. D. P.; Papaefthymiou, G. C.; Holm, R. H. "Subsite-Differentiated Analogues of Native [4Fe-4S]2+ Clusters: Preparation of Clusters with Five- and Six-Coordinate Subsites and Modulation of Redox Potentials and Charge Distributions,” J. Am. Chem. Soc. 1990, 112, 2654-2664.

Holm, R. H. "The Biologically Relevant Oxygen Atom Transfer Chemistry of Molybdenum: From Synthetic Analogue Systems to Enzymes,” Coord. Chem. Rev. 1990, 100, 183-221.

Krüger, H.-J.; Holm, R. H. "Stabilization of Trivalent Nickel in Tetragonal NiS4N2 and NiN6 Environments: Synthesis, Structures, Redox Potentials, and Observations Related to [NiFe]-Hydrogenases,” J. Am. Chem. Soc. 1990, 112, 2955-2963.

Stavropoulos, P.; Carrié, M.; Muetterties, M. C.; Holm, R. H.  "A Reaction Sequence Related to that of Carbon Monoxide Dehydrogenase (Acetyl CoA Synthase): Thioester Formation Mediated at Structurally Defined Nickel Centers,” J. Am. Chem. Soc. 1990, 112, 5385-5387.

Richards, A. J. M.; Thomson, A. J.; Holm, R. H.; Hagen, K. S. "The Magnetic Circular Dichroism Spectra of the Linear Triatomic Clusters [Fe3S4(SR)4]3- in Purple Aconitase and a Synthetic Model,” Spectrochim. Acta 1990, 46A, 987-993.

Ciurli, S.; Carrié, M.; Holm, R. H. "Clusters Containing the [ReFe3S4] Core: An Expansion of the Heterometal Cubane-Type Cluster Series MFe3S4,” Inorg. Chem. 1990, 29, 3493-3501.

Lee, S. C.; Holm, R. H. "Nonmolecular Metal-Chalcogenide-Halide Solids and Their Molecular Cluster Analogues,”  Angew. Chem. 1990, 102, 868; Angew. Chem., Int. Ed. Engl. 1990, 29, 840-856.

Stack, T. D. P.; Weigel, J. A.; Holm, R. H. "The Cavitand Concept in the Synthesis of Subsite-Differentiated Analogues of Biological [4Fe-4S/Se]2+ Clusters: Cluster Capture Reactions, Ligand Conformational Analysis, and the Structure of a Trigonal [4Fe-4Se]2+ Analogue,” Inorg. Chem. 1990, 29, 3745-3760.

Weigel, J. A.; Srivastava, K. K. P.; Day, E. P.; Münck, E.; Holm, R. H. "Isonitrile Binding to a Site-Differentiated Synthetic Analogue of Biological [4Fe-4S] Clusters:  Equilibria, Magnetic Interactions and the Spin-Isolated [3Fe-4S] Cluster Fragment, and the Structure of a Low-Spin Iron(II) Subsite,” J. Am. Chem. Soc. 1990, 112, 8015-8023.

Ciurli, S.; Yu, S.-B.; Holm, R. H.; Srivastava, K. K. P.; Münck, E. "Synthetic NiFe3Q4 Cubane-Type Clusters (S = 3/2) by Reductive Rearrangement of Linear [Fe3Q4(SEt)4]3-
(Q = S, Se),” J. Am. Chem. Soc. 1990, 112, 8169-8171.

Holm, R. H.; Ciurli, S.; Weigel, J. A. "Subsite-Specific Structures and Reactions in Native and Synthetic [4Fe-4S] Cubane-type Clusters,” Prog. Inorg. Chem. 1990, 29, 1-74.

Lee, S. C.; Holm, R. H. "Entry to the Solution Chemistry of Niobium and Tantalum Sulfides:  Synthesis of Soluble Forms of the Tetrathiometalates [MS4]3-,” J. Am. Chem. Soc. 1990, 112, 9654-9655.

1991
Krüger, H.-J.; Peng, G.; Holm, R. H. "Low-Potential Ni(III,II) Complexes: New Systems Based on Tetradentate Amidatethiolates and the Influence of Ligand Structure on Potentials in Relation to the Nickel Site in [NiFe]-Hydrogenases,” Inorg. Chem. 1991, 30, 734-742.

Ciurli, S.; Holm, R. H. "Heterometal Cubane-Type Clusters: A ReFe3S4 Single Cubane Cluster by Cleavage of an Iron-Bridged Double Cubane and the Site-Voided Cubane [Fe3S4] as a Cluster Ligand,” Inorg. Chem. 1991, 30, 743-750.

Snyder, B. S.; Reynolds, M. S.; Holm, R. H.; Papaefthymiou, G. C.; Frankel, R. B.  "Electronic Properties of Monocapped Prismane and Basket Iron-Sulfur Clusters,” Polyhedron 1991, 10, 203-213.

You, J.-F.; Holm, R. H. "[Na9Fe20Se38]9-: A High-Nuclearity Bicyclic Cluster Constructed by the Fusion of Fe2Se2 Rhombs,” Inorg. Chem. 1991, 30, 1431-1433.

Whitener, M. A.; Peng, G.; Holm, R. H.  "Subsite-Differentiated Analogues of Biological [4Fe-4S] Clusters Effected by Binding of a Macrocyclic Polyether Trithiol,” Inorg. Chem. 1991, 30, 2411-2417.

Weigel, J. A.; Holm, R. H. "Intrinsic Binding Properties of a Differentiated Iron Subsite in Analogues of Native [4Fe-4S]2+ Clusters,” J. Am. Chem. Soc. 1991, 113, 4184-4191.

Yu, S.-B.; Papaefthymiou, G. C.; Holm, R. H. "Comprehensive Iron-Selenium-Thiolate Cluster Chemistry,” Inorg. Chem. 1991, 30, 3476-3485.

Yu, S.-B.; Wang, C.-P.; Day, E. P.; Holm, R. H. "A Binuclear Manganese System with Three Isolated Oxidation States: Synthesis, Structures, and Redox Properties of Molecules with an Mn2(OR)2 Bridge Unit Containing Mn(III,III), Mn(III,II), and Mn(II,II),” Inorg. Chem. 1991, 30, 4067-4074.

Stavropoulos, P.; Muetterties, M. C.; Carrié, M.; Holm, R. H. "Structural and Reaction Chemistry of Nickel Complexes in Relation to Carbon Monoxide Dehydrogenase: A Reaction System Simulating Acetyl-Coenzyme A Synthase Activity,” J. Am. Chem. Soc. 1991, 113, 8485-8492.

Liu, H. Y.; Scharbert, B.; Holm, R. H. "An Initial Approach to Biologically Related Bridged Assemblies:  Pyridinethiolate-Linked Fe4S4-Fe Complex Systems,” J. Am. Chem. Soc. 1991, 113, 9529-9539.

1992
You, J.-F.; Papaefthymiou, G. C.; Holm, R. H. "[β-Na2Fe18S30]8- and [Na9Fe20Se38]9-: High-Nuclearity Clusters by Mono- or Bicyclization of Unidimensional Polymeric Fragments and the Existence of Isomeric Monocyclic Clusters,” J. Am. Chem. Soc. 1992, 114, 2697-2710.

Tan, G. O.; Ensign, S. A.; Ciurli, S.; Scott, M. J.; Hedman, B.; Holm, R. H.; Ludden, P. W.; Korszun, Z. R.; Stephens, P. J.; Hodgson, K. O. "On the Structure of the Ni-Fe-S Center of the Carbon Monoxide Dehydrogenase from Rhodospirillum rubrum: an XAS Study,” Proc. Natl. Acad. Sci. USA 1992, 89, 4427-4431.

You, J.-F.; Holm, R. H. "A Topological Method for the Enumeration of Bridging Modes and Connectivity Patterns of the Clusters MmQnLl with Four-Coordinate Metal Sites and Qμ2,3,4 Bridging Atoms,” Inorg. Chem. 1992, 31, 2166-2175.
 
Ciurli, S.; Ross, P. K.; Scott, M. J.; Yu, S.-B.; Holm, R. H. "Synthetic Nickel-Containing Heterometal Cubane-Type Clusters with NiFe3Q4 Cores (Q = S, Se),” J. Am. Chem. Soc. 1992, 114, 5415-5423.

Holm, R. H. "Trinuclear Cuboidal and Heterometallic Cubane-Type Iron-Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology,” Adv. Inorg. Chem. 1992, 38, 1-71.

Gheller, S. F.; Schultz, B. E.; Scott, M. J.; Holm, R. H. "A Broad-Substrate Analogue Reaction System of the Molybdenum Oxotransferases,” J. Am. Chem. Soc. 1992, 114, 6934-6935.

Lee, S. C.; Li, J.; Mitchell, J. C.; Holm, R. H. "The Group 5 Tetrathiometalates: Simplified Syntheses and Structures,” Inorg. Chem. 1992, 31, 4333-4338.

Yaghi, O. M.; Scott, M. J.; Holm, R. H. "Rhenium-Selenium-Chlorine Solid Phases: Cluster Excision and Core Substitution Reactions of Molecular Species,” Inorg. Chem. 1992, 31, 4778-4784.

Zhou, J.; Scott, M. J.; Hu, Z. Peng, G.; Münck, E.; Holm, R. H. "Synthesis and Comparative Reactivity and Electronic Structural Features of [MFe3S4]z+ Cubane-Type Clusters (M = Fe, Co, Ni),” J. Am. Chem. Soc. 1992, 114, 10843-10854.

1993
Yu, S.-B.; Holm, R. H. "Tetrahedral and Square Pyramidal Sulfur-Rich Complexes of Manganese(II),” Polyhedron 1993, 12, 263-266

Holm, R. H.; Donahue, J. P. "A Thermodynamic Scale for Oxygen Atom Transfer Reactions,” Polyhedron 1993, 12, 571-589.

Schultz, B. E.; Gheller, S. F.; Muetterties, M. C.; Scott, M. J.; Holm, R. H. "Molybdenum-Mediated Oxygen Atom Transfer: An Improved Analogue Reaction System of the Molybdenum Oxotransferases,” J. Am. Chem. Soc. 1993, 115, 2714-2722.

Scott, M. J.; Holm, R. H. "Tetranuclear Cuboidal and Hexanuclear Prismatic Iron-Sulfur-Nitrosyl Clusters,” Angew. Chem. 1993, 105, 621; Angew. Chem., Int. Ed. Engl. 1993, 32, 564-566.

Nordlander, E.; Lee, S. C.; Cen, W.; Wu, Z. Y.; Natoli, C. R.; Di Cicco, A.; Filipponi, A.; Hedman, B.; Hodgson, K. O.; Holm, R. H. "The Heterometal Cuboidal Clusters [MFe4S6(PEt3)4Cl] (M = V, Mo): Synthesis, Structural Analysis by Crystallography and EXAFS, and Relevance to the Structure of the Iron-Molybdenum Cofactor of Nitrogenase,” J. Am. Chem. Soc. 1993, 115, 5549-5558.
 
Lee, S. C.; Holm, R. H. "A Synthetic Analogue of the Iron/Copper Bridged Assembly in Cytochrome c Oxidase" J. Am. Chem. Soc. 1993, 115, 5833-5834.

Schultz, B. E.; Holm, R. H. "Kinetics of Oxygen Atom Transfer in an Analogue Reaction System of the Molybdenum Oxotransferases,” Inorg. Chem. 1993, 32, 4244-4248.

Cai, L.; Weigel, J. A.; Holm, R. H. "Analogues of Bridged Biological Active Site Assemblies: the Fe4S4-Sulfide-Heme Unit,” J. Am. Chem. Soc. 1993, 115, 9289-9290.

Lee, S. C.; Holm, R. H. "Fluoride-Bridged Dimers: Binuclear Copper(II) Complexes and Iron(III)-Cu(II) Assemblies,” Inorg. Chem. 1993, 32, 4745-4753.

Cen, W.; Lee, S. C.; Li, J.; MacDonnell, F. M.; Holm, R. H. "Heterometal Dependence of Electron Distributions and Redox Potentials in Clusters with Cubane-Type [MFe3S4]z Cores,” J. Am. Chem. Soc. 1993, 115, 9515-9523.

Lee, S. C.; Holm, R. H. "Synthesis and Characterization of an Asymmetric Bridged Assembly Containg the Unsupported [FeIII-O-CuII] Bridge: An Analogue of the Binuclear Site in Oxidized Cytochrome c Oxidase,” J. Am. Chem. Soc. 1993, 115, 11789-11798.

Lee, S. C.; Scott, M. J.; Kauffmann, K.; Münck, E.; Holm, R. H. "Cyanide Poisoning: An Analogue to the Binuclear Site of Cyanide-Inhibited Cytochrome c Oxidase,” J. Am. Chem. Soc. 1994, 116, 401-402.

1994
Hendrich, M. P.; Day, E. P.; Wang, C.-P.; Snyder, B. S.; Holm, R. H.; Münck, E.  "Ground State Electronic Structures of Binuclear Fe(II) Sites: Experimental Protocol and a Consistent Description of Mössbauer, EPR, and Magnetization Measurements of the Bis(Phenolate)-Bridged Complex [Fe2(salmp)2]2-,” Inorg. Chem. 1994, 33, 2848-2856.

Cai, L.; Holm, R. H. "Synthesis and Electron Delocalization of [Fe4S4]-S-Fe(III) Bridged Assemblies Related to the Exchange-Coupled Catalytic Site of Sulfite Reductases,” J. Am. Chem. Soc. 1994, 116, 7177-7188.

Scott, M. J.; Lee, S. C.; Holm, R. H. "Synthesis and Structural Characterization of Unsupported [FeIII-CN-CuII] Bridges Related to that in Cyanide-Inactivated Cytochrome c Oxidase,” Inorg. Chem. 1994, 33, 4651-4662.

Goh, C.; Weigel, J. A.; Holm, R. H. "The [2:2] Site-Differentiated Clusters [Fe4S4L2(RNC)6] Containing Two Low-Spin Fe(II) Sites,” Inorg. Chem. 1994, 33, 4861-4868.

James, T. L.; Smith, D. M.; Holm, R. H. "Stereoelectronic Preferences in  Electron Transfer Series of Nickel with Tridentate Ligands Containing Hard-Soft Donor Sets,” Inorg. Chem. 1994, 33, 4869-4877.
 
Long, J. R.; Holm, R. H. "Enumeration and Structural Classification of Clusters Derived from Parent Solids: Metal-Chalcogenide Clusters Composed of Edge-Shared Tetrahedra," J. Am. Chem. Soc. 1994, 116, 9987-10002.

Cen, W.; MacDonnell, F. M.; Scott, M. J.; Holm, R. H. "Heterometal Clusters Containing the Cuboidal Fe4S3 Fragment: Synthesis, Electron Distribution, and Reactions,” Inorg. Chem. 1994, 33, 5809-5818

Scott, M. J.; Holm, R. H. "Molecular Assemblies Containing Linear and Bent [FeIII-CN-CuII] Bridged Assemblies: Synthesis, Structures, and Relevance to Cyanide-Inhibited Heme-Copper Oxidases,” J. Am. Chem. Soc. 1994, 116, 11357-11367.

1995
Scott, M. J.; Zhang, H. H.; Lee, S. C.; Hedman, B.; Hodgson, K. O.; Holm, R. H. "Oxygen-Bridged Iron-Copper Assemblies Pertinent to Heme-Copper Oxidases: Synthesis and Structure of an [FeIII-(OH)-CuII] Bridge and EXAFS Multiple Scattering Effects of Linear Oxo and Non-Linear Hydroxo Bridges,” J. Am. Chem. Soc. 1995, 117, 568-569.

Schultz, B. E.; Hille, R.; Holm, R. H. "Direct Oxygen Atom Transfer in the Mechanism of Action of Rhodobacter sphaeroides Dimethylsulfoxide Reductase,” J. Am. Chem. Soc. 1995, 117, 827-828.

Holm, R. H. "Chemical Approaches to Bridged Biological Metal Assemblies,” Pure Appl. Chem. 1995, 67, 217-224.

Long, J. R.; Williamson, A. S.; Holm, R. H. "Dimensional Reduction of Re6Se8Cl2: Clusters Composed of Chloride-Terminated [Re6Q8]2+ (Q = S, Se) Cores,” Angew. Chem. 1995, 107, 256; Angew. Chem., Int. Ed. Engl. 1995, 34, 226-229.

Long, J. R.; Holm, R. H. "Protein-Bound Iron-Sulfur Clusters: Application of a Structural Database,” Inorg. Chim. Acta 1995, 229, 229-239.

MacDonnell, F. M.; Ellison, J. J.; Ruhlandt-Senge, K.; Holm, R. H.; Power, P. P.  "Sterically Encumbered Iron(II) Thiolate Complexes: Synthesis and Structure of Trigonal Planar [Fe(SR)3]1- (R = 2,4,6-tBu3C6H2) and the Mössbauer Spectra of Two- and Three-Coordinate Complexes,” Inorg. Chem. 1995, 34, 1815-1822.

Tucci, G. C.; Holm, R. H. "Nickel-Mediated Formation of Thioesters from Bound Methyl, Thiols, and Carbon Monoxide: A Possible Reaction Pathway for Acetyl-Coenzyme A Synthase Activity in Nickel-Carbon Monoxide Dehydrogenase,” J. Am. Chem. Soc. 1995, 117, 6489-6496.

Franolic, J. F.; Long, J. R.; Holm, R. H. "Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of [W6I14]2-,” J. Am. Chem. Soc. 1995, 117, 8139-8153.

Cai, L.; Segal, B. M.; Long, J. R.; Scott, M. J.; Holm, R. H. "Octanuclear Iron-Sulfur Clusters with Symmetrically Coupled Fe4S4 and Fe4S5 Cores,” J. Am. Chem. Soc. 1995, 117, 8863-8864.

Tian, Z.-Q.; Donahue, J. P.; Holm, R. H. "Synthesis of New Types of Dithiolene Ligands,” Inorg. Chem. 1995, 34, 5567-5572.

Zhou, J.; Holm, R. H. "Synthesis and Metal Ion Incorporation Reactions of the Fe3S4 Cluster,” J. Am. Chem. Soc. 1995, 117, 11353-11354.

1996
Zhou, J.; Hu, Z.; Münck, E.; Holm, R. H. "The Cuboidal Fe3S4 Cluster: Synthesis, Stability, and Geometric and Electronic Structures in a Non-Protein Environment,” J. Am. Chem. Soc. 1996, 118, 1966-1980.

Scott, M. J.; Goddard, C. A.; Holm, R. H. "Molecular Assemblies Containing Unsupported [FeIII-(μ2:η2-RCO2)-CuII] Bridges,” Inorg. Chem. 1996, 35, 2558-2567.

Zhou, C.; Cai, L.; Holm, R. H. "Synthesis of a [Fe4S4]-S-Ferriheme Bridged Assembly Containing an Isobacteriochlorin Component: A Further Analogue of the Active Site of Sulfite Reductase". Inorg. Chem. 1996, 35, 2767-2772.

Long, J. R.; McCarty, L. S.; Holm, R. H. "A Solid State Route to Molecular Clusters: Access to the Solution Chemistry of [Re6Q8]2+ (Q = S, Se) Core-Containing Clusters via Dimensional Reduction,” J. Am. Chem. Soc. 1996, 118, 4603-4616.

James, T. L.; Cai, L.; Muetterties, M. C.; Holm, R. H. "Hydrogenase-Related Nickel Chemistry: Dihydrogen Evolution by Protonation Reactions of Nickel(I),” Inorg. Chem. 1996, 35, 4148-4161.

Goddard, C. A.; Long, J. R.; Holm, R. H. "Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe6S8(PEt3)6]n+ (n = 0-4) Cluster Electron Transfer Series,” Inorg. Chem. 1996, 35, 4347-4354.

Zhang, H. H.; Filipponi, A.; Di Cicco, A.; Lee, S. C.; Scott, M. J.; Holm, R. H.; Hedman, B.; Hodgson, K. O. "Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase: Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors,” Inorg. Chem. 1996, 35, 4819-4828.

Gardner, M. T.; Deinum, G.; Kim, Y.; Babcock, G. T.; Scott, M. J.; Holm, R. H. "Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear FeIII-CN-CuII Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase," Inorg. Chem. 1996, 35, 6878-6884.

Holm, R. H.; Kennepohl, P.; Solomon, E. I. "Structural and Functional Aspects of Metal Sites in Biology,” Chem. Rev. 1996, 96, 2239-2314.

Goh, C.; Segal, B. M.; Huang, J.; Long, J. R.; Holm, R. H. "Polycubane Clusters: Synthesis of [Fe4S4(PR3)4]1+ (R = But, Cy, Pri) and [Fe4S4]0 Core Aggregation Upon Loss of Phosphine," J. Am. Chem. Soc. 1996, 118, 11844-11853.

1997
Huang, J.; Goh, C.; Holm, R. H. "On the Existence in Solution of Doubly Thiolate-Bridged Double Cubanes Containing the Heterometal [MFe3S4] Core (M = Mo, W),” Inorg. Chem. 1997, 36, 356-361.

Zheng, Z.; Long, J. R.; Holm, R. H. "A Basis Set of Re6Se8 Building Blocks and Demonstration of Their Linking Capability: Directed Synthesis of an Re12Se16 Dicluster,” J. Am. Chem. Soc. 1997, 119, 2163-2171.

Zhang, H. H.; Filiponi, A.; Di Cicco, A.; Scott, M. J.; Holm, R. H.; Hedman, B.; Hodgson, K. O. "Multiple Edge XAS Studies of Cyanide-Bridged Iron-Copper Molecular Assemblies Relevant to Cyanide-Inhibited Heme-Copper Oxidases Using Four-Body Multiple-Scattering Analysis,” J. Am. Chem. Soc. 1997, 119, 2470-2478.

Kauffmann, K. E.; Goddard, C. A.; Zang, Y.; Holm, R. H.; Münck, E. "Mössbauer and Magnetization Studies of Heme-Copper Bridged Assemblies Pertinent to Cytochrome c Oxidase,” Inorg. Chem. 1997, 36, 985-993.

Raebiger, J. W.; Crawford, C. A.; Zhou, J.; Holm, R. H. "Reactivity of the Cubane-Type Clusters [(OC)3MFe3S4(SR)3]3-: Interconversion with Cuboidal [Fe3S4]0 Clusters and Electron Transfer,” Inorg. Chem. 1997, 36, 994-1003.

Zhou, J.; Raebiger, J. W.; Crawford, C. A.; Holm, R. H. "Metal Ion Incorporation Reactions of the Cluster [Fe3S4(LS3)]3-, Containing the Cuboidal [Fe3S4]0 Core,” J. Am. Chem. Soc. 1997, 119, 6242-6250.

Beinert, H.; Holm, R. H.; Münck, E. "Iron-Sulfur Clusters: Nature's Modular Multi-Purpose Structures,” Science 1997, 277, 653-659.

Zhou, C.; Holm, R. H. "Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se),” Inorg. Chem. 1997, 36, 4066-4077.

Huang, J.; Mukerjee, S.; Segal, B. M.; Akashi, H.; Zhou, J.; Holm, R. H. "Molybdenum-Iron Sulfide-Bridged Double Cubanes,” J. Am. Chem. Soc. 1997, 119, 8662-8674.
 
Yoo, S. J.; Hu, Z.; Goh, C.; Bominaar, E. L.; Holm, R. H.; Münck, E. "Determination of the Exchange Coupling Constant of an Fe3+Fe3+ Pair in Cubane-Type Iron-Sulfur Clusters,” J. Am. Chem. Soc. 1997, 119, 8732-8733.

Hoveyda, H. A.; Holm, R. H. "Characterization of the Self-Condensation Equilbrium of [Fe4S4(SH)4]2-: Spectroscopic Identification of a Unique Sulfido-Bridged Tricubane Cluster,” Inorg. Chem. 1997, 36, 4571-4578.

Zheng, Z.; Holm, R. H. "Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster,” Inorg. Chem. 1997, 36, 5173-5178.

1998
Willer, M. W.; Long, J. R.; McLauchlan, C. C.; Holm, R. H. "Ligand Substitution Reactions of  [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies,” Inorg. Chem. 1998, 37, 328-333.

Baeg, J.-O.; Holm, R. H. "Covalently Supported Porphyrins as Ligands for the Preparation of Heme a3/CuB Binuclear Active Site Analogues of Heme/Copper Terminal Oxidases and Metallation Under Mild Conditions," J. Chem. Soc., Chem. Commun. 1998, 571-572.

Goh, C.; Holm, R. H. "Synthesis and Structures of the Cuboidal Iron-Sulfur-Nitrosyl-Phosphine Clusters [Fe4S3(PR3)3(NO)4]1+,0,” Inorg. Chim. Acta 1998, 270, 46-54.

Tucci, G. C.; Donahue, J. P.; Holm, R. H. "Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxo Molybdenum and Tungsten Complexes,” Inorg. Chem. 1998, 37, 1602-1608.

Donahue, J. P.; Lorber, C.; Nordlander, E.; Holm, R. H. "Molybdenum and Tungsten Structural Analogues of the Active Sites of the MoIV + [O] → MoVIO Oxygen Atom Transfer Couple of DMSO Reductases,” J. Am. Chem. Soc. 1998, 120, 3259-3260.

Huang, J.; Holm, R. H. "Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe3S4 Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges,” Inorg. Chem. 1998, 37, 2247-2254.

Goh, C.; Nivorozhkin, A.; Yoo, S. J.; Bominaar, E. L.; Münck, E.; Holm, R. H.  "The Mixed-Valence Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites,” Inorg. Chem. 1998, 37, 2926-2932.

Segal, B. M.; Hoveyda, H. R.; Holm, R. H. "Terminal Ligand Assignments Based on Trends in Metal-Ligand Bond Lengths of Cubane-Type [Fe4S4]2+ Clusters,” Inorg. Chem. 1998, 37, 3440-3443.
 
Donahue, J. P.; Holm, R. H. "1,2-Bis(1-adamantyl)dithiete: The First Structurally Characterized Dithiete Unsupported by a Ring or Benzenoid Frame,” Acta Crystallogr. 1998, C54, 1175-1178.

Holm, R. H. “[1:3] Site-Differentiated and Sulfide-Bridged Cubane Clusters in Chemistry and Biology,” Pure Appl. Chem. 1998, 70, 931-938.

Lorber, C.; Donahue, J. P.; Goddard, C. A.; Nordlander, E.; Holm, R. H. "Synthesis, Structures, and Oxo Transfer Reactivity of Bis(dithiolene)tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes,” J. Am. Chem. Soc. 1998, 120, 8102-8112.

Lim, B. S.; Holm, R. H. "Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in vCN Values, and Relation to the Heme-a3/CuB Site in Cyanide-Inhibited Heme-Copper Oxidases,” Inorg. Chem. 1998, 37, 4898-4908.

Donahue, J. P.; Goldsmith, C. R.; Nadiminti, U.; Holm, R. H. "Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes,” J. Am. Chem. Soc. 1998, 120, 12869-12881.

1999
Osterloh, F.; Sanakis, Y.; Staples, R. J.; Münck, E.; Holm, R. H. “Synthesis and Characterization of a Molybdenum-Iron-Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase,” Angew. Chem. Int. Ed. 1999, 38, 2066-2069; Angew.Chem. 1999, 111, 2199-2203.

Laplaza, C. E.; McNamara, J. F.; Kates, S. A.; Holm, R. H. “De Novo Peptide Design as an Approach for the Synthesis of a Structural Representation of the Center A Active Site of Carbon Monoxide Dehyrogenase/Acetyl-CoA Synthase,” In Peptides 1998; Bajkusz, S.; Hudecz, F. Eds.; Akadémiai Kiadó: Budapest, 1999, pp. 320-321.

Nivorozhkin, A. L.; Kates, S. A.; Holm, R. H. “Design and Synthesis of Cyclic Cysteine-Containing Peptides for Transition Metal Incorporation,” In Peptides 1998; Bajkusz, S.; Hudecz, F. Eds.; Akadémiai Kiadó: Budapest, 1999, pp. 336-337.

Segal, B. M.; McNamara, J. F.; Jensen, I.; Kates, S. A.; Holm, R. H. “Design and Synthesis of Cyclic Peptides for Iron-Sulfur Cluster Assembly and Encapsulation,” In Peptides 1998; Bajkusz, S.; Hudecz, F. Eds.; Akadémiai Kiadó: Budapest, 1999, pp. 522-523.

Thapper, A.; Donahue, J. P.; Musgrave, K.; Willer, M. W.; Nordlander, E.; Hedman, B.; Hodgson, K. O.; Holm, R. H. “The Unperturbed Oxo-Sulfido Functional Group cis-MoVIOS, Related to That in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization, and Reactivity Aspects,” Inorg. Chem. 1999, 38, 4104-4114.

Zheng, Z. Z.; Gray, T. G.; Holm, R. H. “Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re6(μ3-Se)8]2+,” Inorg. Chem. 1999, 38, 4888-4895.

Goddard, C. A.; Holm, R. H. “Synthesis and Reactivity Aspects of the Bis(dithiolene) Chalcogenide Series [WIVQ(S2C2R2)2]2- (Q = O, S, Se),” Inorg. Chem. 1999, 38, 5389-5398.

Musgrave, K. B.; Donahue, J. P.; Lorber, C.; Holm, R. H.; Hedman, B.; Hodgson, K. O. "An X-ray Spectroscopic Investigation of Bis(dithiolene)-Molybdenum(IV,V,VI) and
-Tungsten(IV,V,VI) Complexes: Symmetrized Structural Representations of the Active Sites of Molybdoenzymes in the DMSO Reductase Family and of Tungstoenzymes in the AOR and F(M)DH Families,” J. Am. Chem. Soc. 1999, 121, 10297-10307.

Gray, T. G.; Rudzinski, C. M.; Nocera, D. G.; Holm, R. H. “Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re6S8]2+ and [Re6Se8]2+,” Inorg. Chem. 1999, 38, 5932-5933.

2000
Lim, B. S.; Donahue, J. P.; Holm, R. H.  “Synthesis and Structures of Bis(dithiolene)-molybdenum Complexes Related to the Active Sites of the DMSO Reductase Enzyme Family,” Inorg. Chem. 2000, 39, 263-273.

Osterloh, F.; Segal, B. M.; Achim, C.; Holm, R. H. “Reduced Mono-, Di-, and Tetra-Cubane-Type Clusters Containing the [MoFe3S4]2+ Core Stabilized by Tertiary Phosphine Ligation,” Inorg. Chem. 2000, 39, 980-989.

Sung, K.-M.; Holm, R. H.  “Synthesis and Structures of Bis(dithiolene)tungsten(IV) Complexes Related to the Active Sites of Tungstoenzymes,” Inorg. Chem. 2000, 39, 1275-1281.    

Zhou, C.; Raebiger, J. W.; Holm, R. H.  “The Influence of Reduced Charge on the Redox Potentials of Fe4S4 Cubane-Type Clusters in Aprotic Solvents,” Inorg. Chim. Acta 2000, 300-302, 892-902.

Nivorozhkin, A. L.; Segal, B. M.; Musgrave, K. B.; Kates, S. A.; Hedman, B.; Hodgson, K. O.; Holm, R. H. “Metallocyclopeptide Complexes with MII(S⋅Cys)4 Chromophores,” Inorg. Chem. 2000, 39, 2306-2313.

Miao, M.; Willer, M. W.; Holm, R. H. “Oxo/sulfidotungstate(VI) as Precursors to WVIO2, WVIOS, and WVIS2 Complexes and WIV-Dithiolene Chelate Rings,” Inorg. Chem. 2000, 39, 2843-2849.
 
Lim, B. S.; Sung, K.-M.; Holm, R. H. “Structural and Functional Bis(Dithiolene)-Molybdenum/Tungsten Active Site Analogues of the Dimethylsulfoxide Reductase Enzyme Family,” J. Am. Chem. Soc. 2000, 122, 7410-7411.

Musgrave, K. B.; Lim, B. S.; Sung, K.-M.; Holm, R. H.; Hedman, B.; Hodgson, K. O. "X-ray Spectroscopy of Enzyme Active Site Analogues and Related Molecules: Bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) Complexes with Variant Terminal Ligands,” Inorg. Chem. 2000, 39, 5238-5247.

2001
Selby, H. D.; Zheng, Z.; Gray, T. G.; Holm, R. H. "Bridged Multiclusters Derived from the Face-Capped Octahedral [ReIII6(μ3-Se)8]2+ Cluster Core,” Inorg. Chim. Acta 2001, 312, 205-209.

Osterloh, F.; Achim, C.; Holm, R. H. "Reduced Molybdenum-Iron-Sulfur Clusters of Nuclearities Eight and Sixteen, Including a Topological Analogue of the P-Cluster of Nitrogenase,” Inorg. Chem. 2001, 40, 224-232.

Fomitchev, D. V.; Lim, B. S.; Holm, R. H. "Electron Distribution in the Non-Classical Bis(dithiolene) Electron Transfer Series [M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W):  Assessment by Structural, Spectroscopic, and Density Functional Theory Results,” Inorg. Chem. 2001, 40, 645-654.

Lim, B. S.; Holm, R. H. "Bis(dithiolene)molybdenum Analogues Relevant to the DMSO Reductase Enzyme Family: Synthesis, Structures, and Oxygen Atom Transfer Reactions and Kinetics," J. Am. Chem. Soc. 2001, 123, 1920-1930.

Sung, K.-M.; Holm, R. H.  "Oxo Transfer Reactions Mediated by Bis(dithiolene)tungsten Analogues of the Active Sites of Molybdoenzymes in the DMSO Reductase Family: Comparative Reactivity of Tungsten and Molybdenum,” J. Am. Chem. Soc. 2001, 123, 1931-1943.

Daley, C. J. A.; Holm, R. H.  "Reactivity of [Fe4S4(SR)4]2-,3- Clusters with Sulfonium Cations: Analogue Reaction Systems for the Initial Step in Biotin Synthase Catalysis,” Inorg. Chem. 2001, 40, 2785-2793.

Lim, B. S.; Fomitchev, D. V.; Holm, R. H.  "Nickel Dithiolenes Revisited: Structures and Electron Distribution from Density Functional Theory for the Three-Member Electron Transfer Series [Ni(S2C2Me2)2]0,1-,2-,” Inorg. Chem. 2001, 40, 4257-4262.

Achim, C.; Bominaar, E.; Staples, R. J.; Münck, E.; Holm, R. H.  "Influence of Extrinsic Factors on Electron Transfer in a Mixed-Valence Fe2+/Fe3+ Complex: Experimental Results and Theoretical Considerations,” Inorg. Chem. 2001, 40, 4389-4403.
 
Sung, K.-M.; Holm, R. H.  "Substitution and Oxidation Reactions of Bis(dithiolene)-tungsten Complexes Related to Enzyme Sites,” Inorg. Chem. 2001, 40, 4518-4525.

Lim, B. S.; Willer, M. W.; Miao, M.; Holm, R. H.  "Monodithiolene Molybdenum(V,VI) Complexes: A Structural Analogue of the Oxidized Active Site of the Sulfite Oxidase Enzyme Family,” J. Am. Chem. Soc. 2001, 123, 8343-8349.

Thapper, A.; Balmes, O.; Lorber, C.; Svensson, P. H.; Holm, R. H.; Nordlander, E. "Synthesis and Structural Characterization of Two Tungsten(VI) Dioxo Complexes with N,O- and N,S-Coordinating Ligands,” Inorg. Chim. Acta 2001, 321, 162-166.

Laplaza, C. E.; Holm, R. H. "Helix-Loop-Helix Peptides as Scaffolds for the Construction of Bridged Metal Assemblies in Proteins: The Spectroscopic A-Cluster Structure in Carbon Monoxide Dehydrogenase,” J. Am. Chem. Soc. 2001, 123, 10255-10264.

2002
Fomitchev, D. V.; McLauchlan, C. C.; Holm, R. H.  "Heterometal Cubane-Type MFe3S4 Clusters (M = Mo, V) Trigonally Symmetrized with Hydrotris(pyrazolyl)borate(1-) and Tris(pyrazolyl)methanesulfonate(1-) Capping Ligands,” Inorg.  Chem. 2002, 41, 958-966.

Hauser, C.; Bill, E.; Holm, R. H. “Single and Double Cubane Clusters in the Multiple Oxidation States [VFe3S4]3+,2+,1+,” Inorg. Chem. 2002, 41, 1615-1624.

Musgrave, K. B.; Laplaza, C. E.; Holm, R. H.; Hedman, B.; Hodgson, K. O.  “Structural Characterization of Metallopeptides Designed as Scaffolds for the Stabilization of Nickel(II)-Fe4S4 Bridged Assemblies by X-ray Absorption Spectroscopy,” J. Am. Chem. Soc. 2002, 124, 3083-3092.

Laplaza, C. E.; Holm, R. H. “Stability and Nickel Binding Properties of Peptides Designed as Scaffolds for the Stabilization of NiII-Fe4S4 Bridged Assemblies,” J. Biol. Inorg. Chem. 2002, 7, 451-460.         

Sung, K.-M.; Holm, R. H.  "Functional Analogue Reaction Systems of the DMSO Reductase Isoenzyme Family: Probable Mechanism of S-Oxide Reduction in Oxo Transfer Reactions Mediated by Bis(dithiolene)-Tungsten(IV,VI) Complexes,” J. Am. Chem. Soc. 2002, 124, 4312-4320.

Zhou, H.-C.; Su, W.; Achim, C.; Rao, P. V.; Holm, R. H.  "High-Nuclearity Sulfide-Rich Molybdenum-Iron-Sulfide Clusters: Reevaluation and Extension,” Inorg. Chem. 2002, 41, 3191-3201.

Gray, T. G.; Holm, R. H.  "Site-Differentiated Hexanuclear Rhenium(III) Cyanide Clusters [Re6Se8(PEt3)n(CN)6-n]n-4 (n = 4,5) and Kinetics of Solvate Ligand Exchange on the Cubic [Re6Se8]2+ Core,” Inorg. Chem. 2002, 41, 4211-4216.
 
Zhang, Y.; Zuo, J.; Zhou, H.-C.; Holm, R. H.  "Rearrangement of Symmetrical Dicubane Clusters into Topological Analogues of the P-Cluster of Nitrogenase:  Nature's Choice?” J. Am. Chem. Soc. 2002, 124, 14292-14293.

Sanakis, Y.; Yoo, S.-J.; Osterloh, F.; Holm, R. H.; Münck, E.  “Determination of Antiferromagnetic Exchange Coupling in the Tetrahedral Thiolate-Bridged Diferrous Complex [Fe2(SEt)6]2-,” Inorg. Chem. 2002, 41, 7081-7085.

2003
Zhou, H.-C.; Holm, R. H.  "Synthesis and Reactions of Cubane-Type Iron-Sulfur-Phosphine Clusters, Including Soluble Clusters of Nuclearities Eight and Sixteen,” Inorg. Chem. 2003, 42, 11-21.

Lee, S. C.; Holm, R. H.  "Speculative Synthetic Chemistry and the Nitrogenase Problem,” Proc. Natl. Acad. Sci. USA 2003, 100, 3595-3600, 12522-12527.

Zhang, Y.; Holm, R. H.  "Synthesis of a Mo2Fe6S9 Cluster with the Topology of the PN Cluster of Nitrogenase by Rearrangement of an Edge-Bridged Mo2Fe6S8 Double Cubane,” J. Am. Chem. Soc. 2003, 125, 3910-3920.

Gray, T. G.; Rudzinski, C. M.; Meyer, E. E.; Holm, R. H.; Nocera, D. G.  "Spectroscopic and Photophysical Properties of Hexanuclear Rhenium(III) Chalcogenide Clusters,” J. Am. Chem. Soc. 2003, 125, 4755-4770.

Zuo, J.-L.; Zhou, H.-C.; Holm, R. H.  "Vanadium-Iron-Sulfur Clusters Containing the Cubane-Type [VFe3S4] Core Unit: Synthesis of a Cluster with the Topology of the PN Cluster of Nitrogenase,” Inorg. Chem. 2003, 42, 4624-4631.

Szilagyi, R.; Lim, B. S.; Glaser, T.; Holm, R. H.; Hedman, B.; Hodgson, K. O.; Solomon, E. I.  "Description of the Ground State Wave Functions of Ni Dithiolenes Using Sulfur K-edge X-ray Absorption Spectroscopy,” J. Am. Chem. Soc. 2003, 125, 9158-9169.

Jalilehvand, F.; Lim, B. S.; Holm, R. H.; Hedman, B.; Hodgson, K. O.  "X-ray Absorption Spectroscopy of a Structural Analogue of the Oxidized Active Sites in the Sulfite Oxidase Enzyme Family and Related Mo(V) Complexes,” Inorg. Chem. 2003, 42, 5531-5536.

Daley, C. J. A.; Holm, R. H.  "Reactions of Site-Differentiated [Fe4S4]2+,1+ Clusters with Sulfonium Cations: Reactivity Analogues of Biotin Synthase and Other Members of the S-Adenosylmethionine Enzyme Family,” J. Inorg. Biochem. 2003, 97, 287-298.

Partyka, D. V.; Staples, R. J.; Holm, R. H.  "Nucleophilic Reactivity and Oxo/Sulfido Substitution Reactions of the MVIO3 Groups (M = Mo, W),” Inorg. Chem. 2003, 42, 7877-7886.

2004
Holm, R. H.  "Iron-Sulfur Clusters,” In Comprehensive Coordination Chemistry II; Vol. 8; Elsevier: New York, 2004, Section 8.3, pp. 61-90.

Zhang, Y.; Holm, R. H.  "Structural Conversions of Molybdenum-Iron-Sulfur Edge-Bridged Double Cubanes and PN-Type Clusters Topologically Related to the Nitrogenase P-Cluster,” Inorg. Chem. 2004, 43, 674-682.    

Holm, R. H.; Solomon, E. I.  "Preface: Biomimetic Inorganic Chemistry,” Chem. Rev. 2004, 104, 347-348.

Rao, P. V.; Holm, R. H. "Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins,” Chem. Rev. 2004, 104, 527-559.

Lee, S. C.; Holm, R. H.  "The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak Field Clusters,” Chem. Rev. 2004, 104, 1135-1157.

Enemark, J. H.; Cooney, J. J. A.; Wang, J.-J.; Holm, R. H.  "Synthetic Analogues and Reaction Systems Relevant to the Molybdenum and Tungsten Oxotransferases,” Chem. Rev. 2004, 104,1175-1200.

Jiang, J.; Holm, R. H.  “An Expanded Set of Functional Groups in Bis(dithiolene)-tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes, Including WIV-SR and WVIO(SR),” Inorg. Chem. 2004, 43, 1302-1310.

Panda, R.; Zhang, Y.; McLauchlan, C. C.; Venkateswara Rao, P.; Tiago de Oliveira, F. A.; Münck, E.; Holm, R. H. "Initial Structure Modification of Tetrahedral to Planar Nickel(II) in a Nickel-Iron-Sulfur Cluster Related to the C-Cluster of Carbon Monoxide Dehydrogenase,” J. Am. Chem. Soc. 2004,126, 6448-6459.                            

Dey, A.; Glaser, T.; Couture, M. M.-J.; Eltis, L. D.; Holm, R. H.; Hedman, B.; Hodgson, K. O.; Solomon, E. I.  "Ligand K-edge X-ray Absorption Spectroscopy of [Fe4S4]1+,2+,3+ Clusters: Changes in Bonding and Electronic Relaxation upon Redox," J. Am. Chem. Soc., 2004, 126, 8320-8328.  

Rao, P. V.; Bhaduri, S.; Jiang, J.; Holm, R. H.  " Sulfur Bridging Interactions of Cis-Planar NiII-S2N2 Coordination Units with Nickel(II), Copper(I,II), Zinc(II), and Mercury(II): A Library of Bridging Modes, Including NiII(μ2-S)2MI,II Rhombs,” Inorg. Chem. 2004, 43, 5833-5849.

Wang, J.-J.; Kryatova, O. P.; Rybak-Akimova, E. V.; Holm, R. H.  "Comparative Kinetics and Mechanism of Oxygen and Sulfur Atom Transfer Reactions Mediated by Bis(dithiolene) Complexes of Molybdenum and Tungsten,” Inorg. Chem. 2004, 43, 8092 8101.

Partyka, D. V.; Holm, R. H.  "Oxygen/Sulfur Substitution Reactions of Tetraoxometalates Effected by Electrophilic Carbon and Silicon Reagents," Inorg. Chem. 2004, 43, 8609-8616.

Dey, A.; Glaser, T.; Moura, J. J.-G.; Holm, R. H.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. "Ligand K-edge X-ray Absorption Spectroscopy and DFT Calculations on [Fe3S4]0,+ Clusters: Delocalization, Redox, and Effect of the Protein Environment,” J. Am. Chem. Soc. 2004, 126, 16868-16878.

2005
Rao, P. V.; Bhaduri, S.; Jiang, J.; Hong, D.; Holm, R. H.  "On [Fe4S4]2+-(μ2-SR)-MII Bridge Formation in the Synthesis of an A-Cluster Analogue of Carbon Monoxide Dehydrogenase/Acetylcoenzyme A Synthase,” J. Am. Chem. Soc. 2005, 127, 1933-1945.

Jiang, J.; Holm, R. H.  "Reaction Systems Related to Dissimilatory Nitrate Reductase: Nitrate Reduction Mediated by Bis(dithiolene)tungsten Complexes,” Inorg. Chem. 2005,44, 1068-1072.

Hong, D.; Zhang, Y.; Holm, R. H.  "Heterometal Cubane-Type Clusters and Related Clusters Trigonally Symmetrized with Hydrotris(3,5-dimethylpyrazolyl)borate,” Inorg. Chim. Acta 2005, 358, 2303-2311.

Scott, T. A.; Berlinguette, C. P.; Holm, R. H.; Zhou, H.-C.  "Initial Synthesis and Structure of an All-Ferrous Analogue of the Fully Reduced [Fe4S4]0 Cluster of the Nitrogenase Iron Protein,” Proc. Natl. Acad. Sci. USA 2005, 102, 9741-9744.

Panda, R.; Berlinguette, C.; Zhang, Y.; Holm, R. H.  "Synthesis of MFe3S4 Clusters Containing a Planar MII Site (M = Ni, Pd, Pt), a Structural Element in the C-Cluster of Carbon Monoxide Dehydrogenase,” J. Am. Chem. Soc.. 2005, 127, 11092-11101.

Bennett, M. V.; Stoian, S.; Bominaar, E.; Münck, E.; Holm, R. H.  "Initial Members of the Family of Mid-Valent High-Nuclearity Iron Nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-),” J. Am. Chem. Soc. 2005, 127, 12378-12386.

2006
Berlinguette, C. P.; Miyaji, T.; Zhang, Y.; Holm, R. H.  "Precursors to Clusters with the Topology of the PN Cluster of Nitrogenase: Edge-Bridged Double Cubane Clusters [(Tp)2Mo2Fe6S8L4]z – Synthesis, Structures, and Electron Transfer Series,” Inorg. Chem. 2006, 45, 1997-2007.

Friedle, S.; Partyka, D. V.; Bennett, M. V.; Holm, R. H.  "Synthesis of Metal Dithiolene Complexes by Si-S Bond Cleavage of a Bis(silanylsulfanyl)alkene,” Inorg. Chim. Acta 2006, 359, 1427-1434.
 
Wang, J.-J.; Tessier, C.; Holm, R. H.  "Analogue Reaction Systems of Selenate Reductase,” Inorg. Chem. 2006, 45, 2979-2988.

Bennett, M. V.; Holm, R. H.  "Self-Assembly of a Tetradecanuclear Iron Nitride Cluster,” Angew. Chem. Int. Ed. 2006, 45, 5613-5616.

Berlinguette, C. P.; Holm, R. H.  "The Edge-Bridged Mo2Fe6S8 to PN-Type Mo2Fe6S9 Cluster Conversion: Structural Fate of the Attacking Sulfide/Selenide Nucleophile,” J. Am. Chem. Soc. 2006, 128, 11993-12000.

2007
Pesavento, R. P.; Berlinguette, C. P.; Holm, R. H.  "Stabilization of Reduced Molybdenum-Iron-Sulfur Single and Double Cubanes by Cyanide Ligation,” Inorg. Chem. 2007, 46, 510-516.

Sun, J.; Tessier, C.; Holm, R. H.  "Sulfur Ligand Substitution at the Nickel(II) Sites of Cubane-Type and Cubanoid NiFe3S4 Clusters Relevant to the C-clusters of Carbon Monoxide Dehydrogenase,” Inorg. Chem. 2007, 46, 2691-2699.

Groysman, S.; Holm, R. H.  "Synthesis and Structures of Bis(dithiolene)tungsten(IV,VI) Thiolate and Selenolate Complexes: Approaches to the Active Sites of Formate Dehydrogenases,” Inorg. Chem. 2007, 46, 4090-4102.

Wang, J.-J.; Groysman, S.; Lee, S. C.; Holm, R. H.  "Synthesis of Structural Analogues of the Oxidized Sites in the Xanthine Oxidoreductase Enzyme Family," J. Am. Chem. Soc. 2007, 129, 7512-7513.

Hlavinka, M. L.; Miyaji, T.; Staples, R. J.; Holm, R. H.  "Hydroxide-Promoted Core Conversion of Molybdenum-Iron-Sulfur Edge-Bridged Double Cubanes: Oxygen-Ligated Topological PN Clusters,” Inorg. Chem. 2007, 46, 9192-9200.

Tenderholt, A. L.; Szilagyi, R.; Holm, R. H.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. "Sulfur K-edge XAS of WV=O vs. MoV=O Bis(dithiolene) Complexes: Contributions of Relativistic Effects to Electronic Structure and Reactivity of Tungsten Enzymes,” J. Inorg. Biochem. 2007, 101, 1594-1600.    

Wang, J.-J.; Holm, R. H.  "Silylation, Sulfidation, and Benzene-1,2-dithiolate Complexation Reactions of Oxo- and Oxosulfidomolybdates(VI) and -tungstates(VI),” Inorg. Chem. 2007, 46, 11156-11164.

2008
Lee, S. C.; Holm, R. H. "Toward an Expanded Oxygen Atom Transfer Reactivity Scale: Computational Investigation of the Energetics of Oxo Transfer Reaction Couples,” Inorg. Chim. Acta 2008, 361, 1166-1176.

McNaughton, R. L.; Lim, B. S.; Knottenbelt, S. Z.; Holm, R. H.; Kirk, M. L.  "Spectroscopic and Electronic Structure Studies of Symmetrized Models for Reduced Members of the Dimethylsulfoxide Reductase Enzyme Family,” J. Am. Chem. Soc. 2008, 130, 4628-4636.

Pryadun, R.; Holm, R. H.  "A New Class of Binuclear and Trinuclear Iron-Sulfur Clusters Derived from Bis[bis(trimethylsilyl)amido]iron(II),” Inorg. Chem. 2008, 47, 3366-3370.

Scott, T. A.; Holm, R. H.  "VFe3S4 Single and Double Cubane Clusters: Synthesis, Structures, and Dependence of Redox Potentials and Electron Distribution on Ligation and Heterometal,” Inorg. Chem. 2008, 47, 3426-3432.

Tenderholt, A. L.; Szilagyi, R. K.; Holm, R. H.; Hodgson, K. O.; Hedman, B.; Solomon, E. I.  "Electronic Control of the Bailar Twist in Formally d0-d2 Mo tris(dithiolene) Complexes: An S K-edge XAS and DFT Study,” Inorg. Chem. 2008, 47, 6382-6392.

Deng, L.; Holm, R. H.  "Stabilization of Fully Reduced Iron-Sulfur Clusters by Carbene Ligation: The [FenSn]0 Oxidation Levels (n = 4, 8),” J. Am. Chem. Soc. 2008, 130, 9878-9886.

Groysman, S.; Wang, J.-J.; Tagore, R.; Lee, S. C.; Holm, R. H.  "A Biomimetic Approach to Oxidized Sites in the Xanthine Oxidoreductase Family: Synthesis and Stereochemistry of Tungsten(VI) Analogue Complexes,” J. Am. Chem. Soc. 2008, 130, 12794-12807.    
                    
2009
Groysman, S.; Holm, R.  H.  "A Series of Mononuclear Quasi-Two-Coordinate Copper(I) Complexes Employing a Sterically Demanding Thiolate Ligand,” Inorg. Chem.  2009, 48, 621-627.

Groysman, S.; Holm, R.  H.  "Biomimetic Chemistry of Iron, Nickel, Molybdenum and Tungsten in Sulfur-Ligated Protein Sites,” Biochemistry 2009,48, 2310-2320.

Chakrabarti, M.; Deng, L.; Holm, R. H.; Münck, E.; Bominaar, E.  L.  "Mössbauer, Electron Paramagnetic Resonance, and Theoretical Study of a Novel Carbene-based All-ferrous 4Fe-4S Cluster: Electronic Origin and Structural Identification of the Unique Spectroscopic Site," Inorg. Chem. 2009, 48, 2735-2747.
 
Huang, D.; Deng, L.; Sun, J.; Holm, R.  H.  "Cleavage of Ni-(μ2-S)-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions,” Inorg. Chem. 2009, 48, 6159-6166.    

Deng, L.; Bill, E.; Wieghardt, K.; Holm, R. H.  "Cubane-Type Co4S4 Clusters: Synthesis, Redox Series, and Magnetic Ground States,” J. Am. Chem. Soc. 2009, 131, 11213-11221.

2010
Groysman, S.; Majumdar, A.; Zheng, S.-L.; Holm, R. H.  "Reactions of Monodithiolene Tungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase,” Inorg. Chem. 2010, 49, 1082-1089.

Chakrabarti, M.; Deng, L.; Holm, R. H.; Münck, E.; Bominaar, E. L.  "The Modular Nature of All-Ferrous Edge-Bridged Double Cubanes,” Inorg. Chem. 2010, 49, 1647-1650.

Huang, D.; Holm, R. H.  "Reactions of the Terminal NiII-OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular NiII...FeII Bridged Site,” J. Am. Chem. Soc. 2010, 132, 4693-4701.

Tenderholt, A. L.; Wang, J.-J.; Szilagyi, R. K.; Holm, R. H.; Hodgson, K. O.; Hedman, B.; Solomon, E. I.  "Sulfur K-edge X-ray Absorption Spectroscopy and Density Functional Calculations on Mo(IV) and Mo(VI)=O Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in DMSO Reductase and Related Functional Analogues,” J. Am. Chem. Soc. 2010, 132, 8359-8371.

Deng, L.; Majumdar, A.; Lo, W.; Holm, R.  H.  "Stabilization of 3:1 Site-Differentiated Cubane-type Clusters in the [Fe4S4]1+ Core Oxidation State by Tertiary Phosphine Ligation: Synthesis, Core Structural Diversity, and S = 1/2 Ground States,” Inorg. Chem. 2010, 49, 11118-11126.

2011
Huang, D.; Makhlynets, O.; Tan, L. L.; Lee, S. C.; Rybak-Akimova, E.; Holm, R. H.   "Kinetics and Mechanistic Analysis of an Extremely Rapid Carbon Dioxide Fixation Reaction,” Proc. Natl. Acad. Sci. USA 2011, 108, 1222-1227.

Lo, W.; Scott, T. A.; Zhang, P.; Ling, C. C.; Holm, R. H.  "Stabilities of Cubane-Type [Fe4S4(SR)4]2- Clusters in Partially Aqueous Media," J. Inorg. Biochem. 2011, 105, 497-508.

Holm, R. H.; Solomon, E. I.; Majumdar, A.; Tenderholt, A.  "Comparative Molecular Chemistry of Molybdenum and Tungsten and Its Relation to Hydroxylase and Oxotransferase Enzymes,” Coord. Chem. Rev. 2011, 255, 993-1015.
 
Xi, B.; Holm, R. H.  "The [MoFe3S4]2+ Oxidation State: Synthesis, Substitution Reactions, and Structures of Phosphine-Ligated Cubane-Type Clusters with the S = 2 Ground State,” Inorg. Chem. 2011, 50, 6280-6288.

Huang, D.; Makhlynets, O. V.; Tan, L. L.; Lee, S. C.; Rybak-Akimova, E. V.; Holm, R. H. "Fast Carbon Dioxide Fixation by 2,6-Pyridinedicarboxamidato-nickel(II)-hydroxide Complexes: Influence of Changes in Reactive Site Environment on Reaction Rates,” Inorg. Chem. 2011, 50, 10070-10081.

Lo, W.; Huang, S.; Zheng, S.-L.; Holm, R.  H.  "Cubane-type Fe4S4 Clusters with Chiral Thiolate Ligation: Formation by Ligand Substitution, Detection of Intermediates by 1H NMR, and Solid State Structures Including Spontaneous Resolution Upon Crystallization,” Inorg. Chem. 2011, 50, 11082-11090.
 
Majumdar, A.; Holm, R. H.  "Specific Incorporation of Chalcogenide Bridge Atoms in Molybdenum/Tungsten-Iron-Sulfur Single Cubane Clusters,” Inorg. Chem. 2011, 50, 11242-11251.

2012
Tenderholt, A. L.; Hodgson, K. O.; Hedman, B.; Holm, R. H.; Solomon, E. I.  "Substrate and Metal Control of Barrier Heights for Oxo Transfer to Mo and W Bis-dithiolene Sites,” Inorg.  Chem. 2012, 51, 3436-3442.

Zheng, B.; Chen, X.-D.; Zheng, S.-L.; Holm, R. H. "Selenium as a Structural Surrogate of Sulfur: Template-Assisted Assembly of Five Types of Tungsten-Iron-Sulfur/Selenium Clusters and the Structural Fate of Chalcogenide Reactants,” J. Am. Chem. Soc. 2012, 134, 6479-6490.

Lo, W.; Zhang, P.; Ling, C.-C.; Huang, S.; Holm, R. H.  "Formation, Spectroscopic Characterization, and Solution Stability of an [Fe4S4]2+ Cluster Derived from a β-Cyclodextrin Dithiolate,” Inorg. Chem. 2012, 51, 9883-9892.

Zhang, X.; Huang, D.; Chen, Y.-S.; Holm, R. H.  "Synthesis of Binucleating Macrocycles and Their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features,” Inorg. Chem. 2012, 51, 11017-11029.

2013
Tan, L. L.; Holm, R. H.; Lee, S. C.  "Structural Analysis of Cubane-Type Iron Clusters,” Polyhedron 2013, 58, 206-217.

2014
Troeppner, O.; Huang, D.; Holm, R. H.; Ivanović-Burmazović, I.  "Thermodynamics and High-Pressure Kinetics of a Fast Carbon Dioxide Fixation Reaction by a (2,6-Pyridinecarboxamidato-hydroxo)nickel(II) Complex," Dalton Trans. 2014, 43, 5274-5279.

Holm, R. H.; Solomon, E. I.  “Introduction: Bioinorganic Enzymology II,” Chem. Rev. 2014, 114, 3367-3368, 4039-4040.

Lee, S. C.; Lo, W.; Holm, R. H.  "Developments in the Biomimetic Chemistry of Cubane-Type and Higher-Nuclearity Iron-Sulfur Clusters,” Chem. Rev. 2014, 114, 3579-3600.

Ha, Y.; Tenderholt, A.; Holm, R. H.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. "Sulfur K-edge X-ray Absorption Spectroscopy and Density Functional Theory Calculations on Mono-oxo Mo(IV) and Bis-oxo Mo(VI) Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in Sulfite Oxidase,” J. Am. Chem. Soc. 2014, 136, 9094-9105.